Acta Cryst. (2008). E64, m295  [ doi:10.1107/S1600536807068146 ]

Di--thiocyanato-⁴N:N-bis({2,4-dibromo-6-[2-(methylamino)ethyliminomethyl]phenolato-³N,N',O}nickel(II))

H.-W. Lin

Abstract: The title complex, [Ni₂(C₁₁H₁₁Br₂N₂O)₂(NCS)₂], is a thiocyanate-bridged dinuclear nickel(II) complex. The asymmetric unit contains two molecules. Both Ni atoms in each molecule have a square-pyramidal coordination geometry, and each center is bound by one O and two N atoms of one Schiff base ligand and by one N atom of a bridging thiocyanate ligand, which define the basal planes. N atoms from the bridging thiocyanate ligands occupy the apical positions.

Online 4 January 2008

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