[HTML version][PDF version][CIF][3d view][Structure Factors][Supplementary Material][CIF check Report][Issue contents]  [Open access]

[Contents scheme]

Acta Cryst. (2008). E64, m278  [ doi:10.1107/S1600536807067517 ]

Triaquabis(1H-imidazole)bis[[mu]2-2-(oxaloamino)benzoato(3-)]dicopper(II)calcium(II) heptahydrate

C. Mei, K. Li and P. Zhang

Abstract: In the title heterotrinuclear coordination compound, [CaCu2(C9H4NO5)2(C3H4N2)2(H2O)3]·7H2O, the Ca2+ cation is in a pentagonal-bipyramidal geometry and bridges two (1H-imidazole)[2-(oxaloamino)benzoato(3-)]copper(II) units in its equatorial plane. Each CuII atom has a normal square-planar geometry. The molecule has approximate local (non-crystallographic) mirror symmetry and 23 classical hydrogen bonds are found in the crystal structure.

Online 4 January 2008


Copyright © International Union of Crystallography
IUCr Webmaster