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Acta Cryst. (2008). E64, m327  [ doi:10.1107/S1600536807068080 ]

Bis(benzoato-[kappa]2O,O')(2,9-dimethyl-1,10-phenanthroline-[kappa]2N,N')cobalt(II)

P.-Z. Zhao, X.-P. Xuan and Q.-H. Tang

Abstract: In the title compound, [Co(C7H5O2)2(C14H12N2)], the CoII ion is located on a twofold rotation axis and is chelated by a 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand and two benzoate anions in a distorted octahedral geometry. The crystal packing is stabilized by [pi]-[pi] interactions between parallel dmphen ligands of neighbouring molecules, with a face-to-face distance of 3.411 (2) Å.

Online 9 January 2008


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