Acta Cryst. (2008). E64, m496  [ doi:10.1107/S160053680800490X ]

-Hydroxido-bis[(2,2'-bipyridine)tricarbonylrhenium(I)] perrhenate

K. Ruth, T. Morawitz, H.-W. Lerner and M. Bolte

Abstract: The title compound, [Re₂(OH)(C₁₀H₈N₂)₂(CO)₆][ReO₄], is a mixed-valence rhenium compound containing discrete anions and cations. The Re^I atoms are in a slightly distorted octahedral environment, whereas the Re^VII atoms show the typical tetrahedral coordination mode. The dihedral angle between the two bipyridine groups is 34.3 (7)°.

Online 27 February 2008

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