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Acta Cryst. (2008). E64, o576-o577  [ doi:10.1107/S1600536808003905 ]

4,4',6,6'-Tetra-tert-butyl-2,2'-[1,2-phenylenebis(nitrilomethylidyne)]diphenol acetone solvate

N. E. Eltayeb, S. G. Teoh, S. Chantrapromma, H.-K. Fun and R. Adnan

Abstract: In the Schiff base molecule of the title compound, C36H48N2O2·C3H6O, the central benzene ring makes dihedral angles of 46.64 (10) and 49.34 (10)° with the two outer benzene rings, and the two outer benzene rings form an angle of 39.13 (8)°. There are two intramolecular O-H...N hydrogen bonds involving the two hydroxy groups, which generate S(6) ring motifs. In the crystal structure, the Schiff base molecules are linked into a chain along the a axis by C-H...[pi] interactions. The acetone solvent molecules are attached to the chain via C-H...O hydrogen bonds.

Online 13 February 2008


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