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Acta Cryst. (2008). E64, m460-m461  [ doi:10.1107/S1600536808003747 ]

Bis(4-fluorobenzoato-[kappa]2O,O')bis(nicotinamide-[kappa]N1)zinc(II) monohydrate

T. Hökelek, N. Çaylak and H. Necefoglu

Abstract: The title compound, [Zn(C7H4FO2)2(C6H6N2O)2]·H2O, is a monomeric complex. It contains two 4-fluorobenzoate and two nicotinamide ligands and one uncoordinated water molecule. The 4-fluorobenzoates act as bidentate chelating ligands, while the nicotinamides are monodentate. The six-coordinate geometry around the ZnII atom may be described as highly distorted octahedral, with the two nicotinamide ligands arranged cis. Intermolecular O-H...O and N-H...O hydrogen bonds link the molecules into a supramolecular structure.

Online 6 February 2008


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