![[HTML version]](/e/graphics/htmlborder.gif)
![[PDF version]](/e/graphics/pdfborder.gif)
![[CIF]](/e/graphics/cifborder.gif)
![[3d view]](/e/graphics/3dviewborder.gif)
![[Structure Factors]](/e/graphics/structurefactorsborder.gif)
![[Supplementary Material]](/e/graphics/supplementarymaterialsborder.gif)
![[CIF check Report]](/e/graphics/checkcifborder.gif)
![[Issue contents]](/e/graphics/issuecontentsborder.gif)
![[Open access]](/e/graphics/free.gif)
![[Contents scheme]](sj2461contents.gif)
Acta Cryst. (2008). E64, m468-m469 [ doi:10.1107/S1600536808003620 ]
![[mu]](/logos/entities/mu_rmgif.gif)
4-benzene-1,2-dicarboxylato)(3-benzene-1,2-dicarboxylato)tetrathulium(III)]Abstract: The title compound, [Tm4(C8H4O4)6(H2O)2]n, has been synthesized hydrothermally. The asymmetric unit has four unique TmIII ions that are six-, seven-, eight- and nine-coordinate. The cations are interconnected by bridging benzene-1,2-dicarboxylate (BDC) anions to form an infinite two-dimensional framework, in which the BDC ligands adopt three different coordination modes. Adjacent sheets are further packed to form a three-dimensional supramolecular framework through O-H
O hydrogen bonds.
Online 13 February 2008
Copyright © International Union of Crystallography
IUCr Webmaster