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Acta Cryst. (2008). E64, m516  [ doi:10.1107/S1600536808004431 ]

Tetrakis([mu]-2,4-difluorobenzoato)bis[(2,4-difluorobenzoato)(1,10-phenanthroline)gadolinium(III)]

S.-B. Wang, H.-M. He, S. Li and K. Tang

Abstract: In the title compound, [Gd2(C7H3F2O2)6(C12H8N2)2], the asymmetric unit comprises one Gd3+ cation chelated by two 2,4-difluorobenzoate and one 1,10-phenanthroline ligands. Two cations are linked into a centrosymmetric dimer via three bridging carboxylate groups of 2,4-difluorobenzoate ligands. Each Gd3+ ion is nine-coordinated by seven O atoms and two N atoms.

Online 5 March 2008


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