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Acta Cryst. (2008). E64, m531-m532  [ doi:10.1107/S1600536808006090 ]

(2,2'-Bipyridine-[kappa]2N,N'){[(3-methoxy-2-oxidobenzylidene-[kappa]O2)hydrazono]methanolato-[kappa]2N2,O}dimethyltin(IV)

S. Shuja, S. Ali, M. N. Tahir, N. Khalid and I. U. Khan

Abstract: In the crystal structure of the title compound, [Sn(CH3)2(C9H8N2O3)(C10H8N2)], the Sn atom exhibits a pentagonal bipyramidal coordination geometry defined by two C, three N and two O atoms. The bond distances for Sn-C, Sn-N and Sn-O are in the ranges 2.097 (3)-2.098 (3), 2.298 (2)-2.623 (2) and 2.157 (2)-2.266 (2) Å, respectively. The molecular structure of the monomeric compound is stabilized by three intramolecular C-H...O hydrogen bonds, all involving bipyridine C-H groups.

Online 7 March 2008


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