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Acta Cryst. (2008). E64, m518-m519  [ doi:10.1107/S1600536808005643 ]

Bis[benzyl N'-(3-phenylprop-2-enylidene)hydrazinecarbodithioato-[kappa]2N',S]zinc(II)

H.-K. Fun, S. Chantrapromma, M. T. H. Tarafder, M. T. Islam, C. M. Zakaria and M. A. A. A. A. Islam

Abstract: In the title ZnII complex, [Zn(C17H15N2S2)2], the ZnII atom lies on a twofold rotation axis. It exists in a tetrahedral geometry, chelated by two deprotonated Schiff base ligands. The dihedral angle between each ligand is 71.48 (8)°. Molecules are connected by weak C-H...S intermolecular interactions into chains along the c axis. The crystal structure is further stabilized by C-H...[pi] interactions involving the phenyl ring of the 3-phenylprop-2-enylidene unit.

Online 5 March 2008


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