Acta Cryst. (2008). E64, m557  [ doi:10.1107/S160053680800679X ]

(Pyridino-15-crown-5-⁵N,O,O',O'',O''')bis(thiocyanato-N)manganese(II)

C. Li, Z. Feng, D. Li and D. Wang

Abstract: The title complex, [Mn(NCS)₂(C₁₃H₁₉NO₄)] {systematic name: [3,6,9,12-tetraoxa-18-azabicyclo[12.3.1]octacosa-14(18),15,17-triene-⁵N,O,O',O'',O''']bis(thiocyanato-N)manganese(II)}, was obtained by the reaction of MnCl₂·4H₂O and NaSCN with pyridino-15-crown-5. The Mn²⁺ center has a distorted pentagonal bipyramidal coordination geometry, coordinated by four O atoms and one N atom of the pyridino-15-crown-5 molecule, and by the N atoms of the two NCS^- ligands.

Online 14 March 2008

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