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Acta Cryst. (2008). E64, m599-m600  [ doi:10.1107/S1600536808007939 ]

[(2S)-2-(3,5-Dichloro-2-oxidobenzylideneamino)-3-(4-hydroxyphenyl)propionato-[kappa]3O,N,O'](dimethylformamide-[kappa]O)copper(II)

M.-X. Tan, Z.-F. Chen, Z. Neng and H. Liang

Abstract: In the title complex, [Cu(C16H11Cl2NO4)(C3H7NO)] , the CuII atom is coordinated by two O atoms and one N atom from the tridentate ligand L2- {LH2 = (2S)-[2-(3,5-dichloro-2-hydroxybenzylidene)imino]-3-(4-hydroxyphenyl)propionic acid} and one O atom from a dimethylformamide molecule, resulting in a slightly distorted square-planar geometry. The structure forms a one-dimensional chain through weak coordination bonds [Cu...O 3.080 (1), Cu...Cl 3.269 (1) Å] and a three-dimensional network through O-H...O and C-H...O hydrogen bonds.

Online 29 March 2008


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