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Acta Cryst. (2008). E64, o837  [ doi:10.1107/S1600536808009215 ]

3-(4-Chlorophenylsulfonyl)-2-methylnaphtho[1,2-b]furan

H. D. Choi, P. J. Seo, B. W. Son and U. Lee

Abstract: The title compound, C19H13ClO3S, was prepared by the oxidation of 3-(4-chlorophenylsulfanyl)-2-methylnaphtho[1,2-b]furan with 3-chloroperoxybenzoic acid. The 4-chlorophenyl ring makes a dihedral angle of 68.59 (5)° with the plane of the naphthofuran fragment. The crystal structure is stabilized by [pi]-[pi] interactions between the benzene rings of neighbouring molecules [centroid-centroid distance = 3.635 (3) Å], and by C-H...[pi] interactions between a methyl H atom and the furan ring of an adjacent molecule. In addition, the crystal structure exhibits intermolecular C-H...O interactions.

Online 16 April 2008


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