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Volume 64 
Part 5 
Page m748  
May 2008  

Received 23 April 2008
Accepted 24 April 2008
Online 30 April 2008


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Key indicators
Single-crystal X-ray study
T = 299 K
Mean [sigma](C-C) = 0.006 Å
R = 0.040
wR = 0.114
Data-to-parameter ratio = 16.1
Details

Chlorido(ethyldiphenylphosphine-[kappa]P)(1-pyrrolidinecarbodithioato-[kappa]2S,S')nickel(II)

Anna Kropidlowska,a* Ilona Turowska-Tyrkb and Barbara Beckera

aDepartment of Inorganic Chemistry, Chemical Faculty, Gdansk University of Technology, 11/12 G. Narutowicza St., 80-952 PL Gdansk, Poland, and bInstitute of Physical and Theoretical Chemistry, Chemical Faculty, Wroclaw University of Technology, 27 Wybrzeze Wyspianskiego, 50-370 PL Wroclaw, Poland
Correspondence e-mail: anna@urethan.chem.pg.gda.pl

In the crystal structure of the title complex, [Ni(C5H8NS2)Cl(C14H15P)], the Ni atom is coordinated by an S,S'-chelating dithiocarbamate, a chloride and a diphenylethylphosphine ligand in a distorted square-planar arrangement.

Related literature

For related literature, see: Allen (2002[Allen, F. H. (2002). Acta Cryst. B58, 380-388.]); Darkwa et al. (1999[Darkwa, J., Osei-Twum, E. Y. & Litrja, L. A. (1999). Polyhedron, 18, 1115-1122.]); Kropidlowska, Chojnacki et al. (2007[Kropidlowska, A., Chojnacki, J., Golaszewska, J. & Becker, B. (2007). Acta Cryst. E63, m1643.]); Kropidlowska, Janczak et al. (2007[Kropidlowska, A., Janczak, J., Golaszewska, J. & Becker, B. (2007). Acta Cryst. E63, m1947.]); Pastorek et al. (1996[Pastorek, R., Trávnícek, Z., Kvapilova, E., Sindelár, Z. & Brezina, F. (1996). Polyhedron, 15, 3691-3695.], 1999[Pastorek, R., Trávnícek, Z., Sindelár, Z. & Brezina, F. (1999). Transition Met. Chem. 24, 304-305.]); Reger & Collins (1995[Reger, D. L. & Collins, J. E. (1995). Inorg. Chem. 34, 2473-2475.]).

[Scheme 1]

Experimental

Crystal data

  • [Ni(C5H8NS2)Cl(C14H15P)]

  • Mr = 454.63

  • Monoclinic, P 21 /c

  • a = 6.5218 (5) Å

  • b = 19.1695 (15) Å

  • c = 16.6178 (14) Å

  • [beta] = 90.786 (6)°

  • V = 2077.4 (3) Å3

  • Z = 4

  • Mo K[alpha] radiation

  • [mu] = 1.34 mm-1

  • T = 299 (2) K

  • 0.50 × 0.21 × 0.17 mm
Data collection

  • Kuma KM-4-CCD diffractometer

  • Absorption correction: refined from [Delta]F (Walker & Stuart, 1983[Walker, N. & Stuart, D. (1983). Acta Cryst. A39, 158-166.]) Tmin = 0.553, Tmax = 0.804

  • 10912 measured reflections

  • 3637 independent reflections

  • 2989 reflections with I > 2[sigma](I)

  • Rint = 0.042
Refinement

  • R[F2 > 2[sigma](F2)] = 0.040

  • wR(F2) = 0.113

  • S = 1.08

  • 3637 reflections

  • 226 parameters

  • H-atom parameters constrained

  • [Delta][rho]max = 0.57 e Å-3

  • [Delta][rho]min = -0.35 e Å-3

Data collection: CrysAlis CCD (Oxford Diffraction, 2003[Oxford Diffraction (2003). CrysAlis CCD and CrysAlis RED. Oxford Diffraction Poland, Wroclaw, Poland.]); cell refinement: CrysAlis CCD; data reduction: CrysAlis RED (Oxford Diffraction, 2003[Oxford Diffraction (2003). CrysAlis CCD and CrysAlis RED. Oxford Diffraction Poland, Wroclaw, Poland.]); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: ORTEP-3 (Farrugia, 1997[Farrugia, L. J. (1997). J. Appl. Cryst. 30, 565.]) and Mercury (Macrae et al., 2006[Macrae, C. F., Edgington, P. R., McCabe, P., Pidcock, E., Shields, G. P., Taylor, R., Towler, M. & van de Streek, J. (2006). J. Appl. Cryst. 39, 453-457.]); software used to prepare material for publication: SHELXL97.

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: AT2563 ).

Acknowledgements

The authors acknowledge Professor J. Pikies for his donation of the sample of NiCl2(PPh2Et)2 and J. Golaszewska for her help during the crystallization. This work was supported by the Ministry of Science and Higher Education (Poland), grant No. 1 T09A 117 30. A. Kropidlowska thanks the Foundation for Polish Science for a fellowship.

References

Allen, F. H. (2002). Acta Cryst. B58, 380-388.  [CrossRef] [details]
Darkwa, J., Osei-Twum, E. Y. & Litrja, L. A. (1999). Polyhedron, 18, 1115-1122.  [CrossRef]
Farrugia, L. J. (1997). J. Appl. Cryst. 30, 565.  [CrossRef] [details]
Kropidlowska, A., Chojnacki, J., Golaszewska, J. & Becker, B. (2007). Acta Cryst. E63, m1643.  [CrossRef] [details]
Kropidlowska, A., Janczak, J., Golaszewska, J. & Becker, B. (2007). Acta Cryst. E63, m1947.  [CrossRef] [details]
Macrae, C. F., Edgington, P. R., McCabe, P., Pidcock, E., Shields, G. P., Taylor, R., Towler, M. & van de Streek, J. (2006). J. Appl. Cryst. 39, 453-457.  [CrossRef] [ChemPort] [details]
Oxford Diffraction (2003). CrysAlis CCD and CrysAlis RED. Oxford Diffraction Poland, Wroclaw, Poland.
Pastorek, R., Trávnícek, Z., Kvapilova, E., Sindelár, Z. & Brezina, F. (1996). Polyhedron, 15, 3691-3695.  [CrossRef]
Pastorek, R., Trávnícek, Z., Sindelár, Z. & Brezina, F. (1999). Transition Met. Chem. 24, 304-305.  [CrossRef]
Reger, D. L. & Collins, J. E. (1995). Inorg. Chem. 34, 2473-2475.  [CrossRef]
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.  [CrossRef] [details]
Walker, N. & Stuart, D. (1983). Acta Cryst. A39, 158-166.  [CrossRef] [details]

Acta Cryst (2008). E64, m748  [ doi:10.1107/S1600536808011860 ]

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