Acta Cryst. (2008). E64, m701-m702  [ doi:10.1107/S160053680801074X ]

catena-Poly[[[bis[4-(1H-1,3,7,8-tetraazacyclopenta[l]phenanthren-2-yl)phenol-²N⁷,N⁸]manganese(II)]--naphthalene-1,4-dicarboxylato-²O¹:O⁴] naphthalene-1,4-dicarboxylic acid hemisolvate monohydrate]

H.-D. Li, X.-Y. Li, M.-L. Xu and S. W. Ng

Abstract: The 1,4-dicarboxylate dianions in the title compound, [Mn(C₁₂H₆O₄)(C₁₉H₁₂N₄O)₂]·0.5C₁₂H₈O₄·H₂O, bond to two 4-(1H-1,3,7,8-tetraazacyclopenta[l]phenanthren-2-yl)phenol-chelated Mn atoms to form a chain that features the metal atom in an octahedral coordination geometry. Adjacent chains interact with the uncoordinated water molecules to form a three-dimensional network. The naphthalene-1,4-dicarboxylic acid solvent molecule, which is disordered about a centre of inversion, occupies the space within the network but is not bonded to the network. One NH group is disordered equally over two positions.

Online 23 April 2008

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