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Acta Cryst. (2008). E64, m695  [ doi:10.1107/S1600536808010751 ]

([mu]-4-Methylbenzenethiolato-[kappa]2S:S)bis[carbonyl([eta]5-cyclopentadienyl)molybdenum(II)]

R. C. S. Wong, M. L. Ooi and S. W. Ng

Abstract: The asymmetric unit of the title compound, [Mo2(C5H5)2(C7H7S)2(CO)2], consists of two half-molecules, each molecule lying on a centre of symmetry. The thiolate groups function as bridges between the MoII atoms, which adopt a quasi-octahedral geometry. In the octahedral environment the two ligating S atoms are in a cis arrangement.

Online 23 April 2008


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