Acta Cryst. (2008). E64, m703  [ doi:10.1107/S1600536808010763 ]

Bis[1,3-bis(diphenylphosphino)propane-²P:P']silver(I) bis(chlorodifluoroacetato-O)triphenylstannate(IV)

Y. Y. Teo, K. M. Lo and S. W. Ng

Abstract: In the title salt, [Ag(C₂₇H₂₆P₂)₂][Sn(C₆H₅)₃(C₂ClF₂O₂)], the Ag^I atom exists in a tetrahedral coordination geometry formed by four P atoms [Ag-P = 2.460 (1)-2.501 (1) Å], whereas the Sn^IV atom exists in a trans-trigonal-bipyramidal coordination geometry formed by two O [Sn-O = 2.208 (3) and 2.233 (3) Å] and three C atoms [Sn-C = 2.115 (4)-2.128 (4) Å;( C-Sn-C)= 360.0 (6)°].

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