Acta Cryst. (2008). E64, m608  [ doi:10.1107/S1600536808004881 ]

Decacarbonyl-1³C,2³C,3⁴C--hydrido-1:2²H:H-(-quinoline-2-thiolato-1:2²S:S)diosmium(I)osmium(0)(3 Os-Os)

Y. Sun, X.-B. Li and B.-W. Sun

Abstract: The title compound, [Os₃(C₉H₆NS)H(CO)₁₀], contains a nearly equilateral triangle of Os atoms. Two of the Os atoms are bridged by an S atom of the quinoline-2-thiolate ligand. Ten carbonyl groups complete the cluster, resulting in a distorted octahedral geometry for each Os atom. The hydride atom, which was located in a difference Fourier map and refined isotropically, bridges the shortest Os-Os edge.

Online 2 April 2008

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