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Acta Cryst. (2008). E64, m747  [ doi:10.1107/S1600536808012373 ]

Bis(benzo-15-crown-5-[kappa]5O)strontium bis(triiodide)

C. Walbaum, I. Pantenburg and G. Meyer

Abstract: The title compound, [Sr(C14H20O5)2](I3)2, obtained by slow evaporation of an ethanol/dichloromethane solution (1:1) of SrCl2, benzo-15-crown-5 and I2, is built of sandwich-like [Sr(benzo-15-crown-5)2]2+ cations and isolated linear I3- anions which are arranged in alternating layers parallel to (010). The triiodide anions are located in general positions, whereas the cations are located on centres of inversion.

Online 30 April 2008


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