Acta Cryst. (2008). E64, m607 [ doi:10.1107/S1600536808008386 ]
Abstract: The title compound, [Cu(C5H5N)2(C18H15P)2]BF4, crystallizes as discrete [(PPh3)2(py)2Cu]+ cations and [BF4]- anions and is isostructural with the analogous perchlorate salt. The anion is located in close proximity to the pyridine ligands with weak C-HF interactions apparent. The P2CuN2 coordination geometry is pseudo-tetrahedral, with P-Cu-P and N-Cu-N angles of 116.02 (6) and 101.5 (2)°, respectively.
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