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Acta Cryst. (2008). E64, m679  [ doi:10.1107/S1600536808010076 ]

Tetraaquabis(pyridine-3-sulfonato-[kappa]N)nickel(II)

B.-Y. Zhang, J.-J. Nie and D.-J. Xu

Abstract: In the molecule of the title compound, [Ni(C5H4NO3S)2(H2O)4], the NiII cation is located on an inversion center and is coordinated by four water molecules and two pyridine-3-sulfonate anions with an NiN2O4 distorted octahedral geometry. The face-to-face separation of 3.561 (5) Å between parallel pyridine rings indicates the existence of weak [pi]-[pi] stacking between the pyridine rings. The structure also contains intermolecular O-H...O hydrogen bonding and weak C-H...O hydrogen bonding.

Online 16 April 2008


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