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Acta Cryst. (2008). E64, m732  [ doi:10.1107/S1600536808006466 ]

Bis(2-aminopyrimidine-[kappa]N1)dibromidozinc(II)

Y. Qu, S. M. Zhang, X. Z. Wu, H. Zhang and Z. D. Lin

Abstract: The title compound, [ZnBr2(C4H5N3)2], is a mononuclear complex in which the ZnII ions have distorted tetrahedral coordination geometry. The ZnII ion binds to two N atoms from two different 2-aminopyrimidine ligands and two bromide ions. N-H...N hydrogen bonds link the molecules to form a one-dimensional supramolecular structure. The supramolecular chains are parallel to each other and N-H...Br hydrogen bonds link them into a two-dimensional network in the ac plane. Additionally, there are strong [pi]-[pi] interactions [centroid-centroid distance = 3.403 (3) Å].

Online 30 April 2008


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