(IUCr) Crystallography Journals Online

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Acta Cryst. (2008). E64, m704-m705 [ doi:10.1107/S1600536808010787 ]

Poly[[₄-naphthalene-1,4-dicarboxylato-⁴O:O':O'':O'''-₂-naphthalene-1,4-dicarboxylato-⁴O,O':O'',O'''-bis(2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-²N⁷,N⁸)dimanganese(II)] N,N-dimethylformamide solvate]

H.-D. Li, Y. Liu, M.-L. Xu and S. W. Ng

Abstract: One of the two 1,4-dicarboxylate dianions in the title compound, [Mn₂(C₁₂H₆O₄)₂(C₁₉H₁₂N₄)₂]·C₃H₇NO, uses its two carboxylate groups to chelate two N-heterocycle-chelated Mn atoms; the other 1,4-dicarboxylate dianion binds to four such metal centers. The octahedrally coordinated Mn atoms are linked through the two dianions into a layer motif; the dimethylformamide molecules occupy the spaces between adjacent layers. Ten C atoms and attached H atoms of one dianion are disordered equally over two positions.

Online 23 April 2008

Poly[[4-naphthalene-1,4-dicarboxylato-4O:O':O'':O'''-2-naphthalene-1,4-dicarboxylato-4O,O':O'',O'''-bis(2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-2N7,N8)dimanganese(II)] N,N-dimethylformamide solvate]

H.-D. Li, Y. Liu, M.-L. Xu and S. W. Ng

Poly[[₄-naphthalene-1,4-dicarboxylato-⁴O:O':O'':O'''-₂-naphthalene-1,4-dicarboxylato-⁴O,O':O'',O'''-bis(2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-²N⁷,N⁸)dimanganese(II)] N,N-dimethylformamide solvate]