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Acta Cryst. (2008). E64, m708  [ doi:10.1107/S1600536808010799 ]

Poly[bis([mu]2-benzyloxyacetato-[kappa]3O,O':O'')cadmium(II)]

J.-W. Liu and S. W. Ng

Abstract: The title cadmium derivative of benzyloxyacetic acid, [Cd(C9H9O3)2]n, exists as a [mu]2-carboxylate-bridged layer network. Two benzyloxyacetate units each chelate the metal through a carboxylate as well as through the ether O atoms; the metal is also coordinated by the double-bond carbonyl O atom of two adjacent benzyloxyacetate units in an octahedral geometry. The metal atom lies on a special position of 2 site symmetry. The phenyl group is disordered equally over two positions.

Online 23 April 2008


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