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Acta Cryst. (2008). E64, m729 [ doi:10.1107/S1600536808011677 ]
![[kappa]](/logos/entities/kappa_rmgif.gif)
N3)manganese(II) triaquatris(1H-imidazole-N3)manganese(II) bis(naphthalene-1,4-dicarboxylate)Abstract: In the crystal structure of the title compound, [Mn(C3H4N2)6][Mn(C3H4N2)3(H2O)3](C12H6O4)2, there are uncoordinated naphthalenedicarboxylate dianions and two kinds of MnII complex cations, both assuming a distorted octahedral geometry. One MnII cation is located on an inversion center and is coordinated by six imidazole molecules, while the other MnII cation is located on a twofold rotation axis and is coordinated by three water molecules and three imidazole units. The naphthalenedicarboxylate dianions are linked to both MnII complex cations via O-H
O and N-HO hydrogen bonding, but no ![[pi]](/logos/entities/pi_rmgif.gif)
- stacking is observed between aromatic rings in the crystal structure.
Online 26 April 2008
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