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Acta Cryst. (2008). E64, o876-o877 [ doi:10.1107/S1600536808010465 ]
Abstract: In the title compound, C20H21N2+.I-·1.5H2O, the cation exists in the E configuration and is not planar. The dihedral angle between the quinolinium and dimethylaminophenyl rings is 9.26 (6)°. The O atom of one of the solvent water molecules lies on a twofold rotation axis. In the crystal structure, the cations form one-dimensional zigzag chains along the [001] direction. The cations are linked to water molecules and iodide ions through weak C-H
O and C-H
I interactions, respectively. Water molecules and iodide ions form O-H
O and O-H
I hydrogen bonds, which stabilize the crystal structure. A C-H
interaction is also present.
Online 18 April 2008
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