Acta Cryst. (2008). E64, o898  [ doi:10.1107/S1600536808010817 ]

Tris[2-(deuteriomethylsulfanyl)phenyl]phosphine deuteriochloroform 0.125-solvate

R. C. S. Wong, M. L. Ooi, H. Sakurai and S. W. Ng

Abstract: The title deuterated tripodal phosphine, C₂₁H₁₂D₉PS₃·0.125CDCl₃, crystallizes as two independent molecules, one of which lies on a general position and the other about a threefold rotation axis, and as a deuteriochloroform solvate. The solvent molecule is disordered about a site of symmetry 3, so that the ratio of phosphine to solvent is 8:1. The P atom adopts a pyramidal coordination geometry.

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