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Acta Cryst. (2008). E64, m819    [ doi:10.1107/S1600536808014128 ]

Bis[1,2-bis(diphenylphosphino)ethane-[kappa]2P:P']silver(I) bis(chlorodifluoroacetato-[kappa]O)(4-chlorophenyl)diphenylstannate(IV)

Y. Y. Teo, K. M. Lo and S. W. Ng

Abstract top

In the title salt, [Ag(C26H24P2)2][Sn(C2ClF2O2)2(C6H5)2(C6H4Cl)], the AgI atom has a tetrahedral and the SnIV atom a trans-trigonal-bipyramidal coordination geometry. In the anion, the chloro substituent is disordered over two rings (occupancy ratio 0.81:0.19); the two chlorodifluoromethyl groups are also disordered over two sites for their halogen atoms (occupancy ratios 0.72:0.28 and 0.70:0.30).

Comment top

This study continues with studies on bis[1,2-bis(diphenylphosphine)ethane]silver bis(chlorodifluoroacetato)triorganostannates (Teo et al., 2007, 2008). In the present study, the [Ag(Ph2CH2CH2Ph2)2] cation is the counterion for [Sn(C6H4Cl)Ph2(ClF2CCO2)2] (Scheme I). The silver(I) atom shows tetrahedral and the tin atom trans-trigonal bipyramidal coordination (Fig. 1).

Related literature top

For other [1,2-bis(diphenylphosphine)ethane]silver bis(chlorodifluoroacetato)triorganostannates, see: Teo et al. (2007; 2008). The structural chemistry of organotin carboxylates has been reviewed by Tiekink (1991, 1994).

Experimental top

(4-Chlorophenyl)diphenyltin hydroxide (0.20 g, 0.5 mmol) and chorodifluoroacetic acid (0.05 ml, 0.5 mmol) were dissolved in dichloromethane/methanol (25 ml). The mixture was heated until the hydroxide dissolved completely. Another solution containing 1,2-bis(diphenylphosphino)ethane (0.40 g, 1.0 mmol) and silver trifluoroacetate (0.11 g, 0.5 mmol) was prepared; this was also heated until the reagents dissolved completely. The two solutions were mixed; crystals were obtained by allowing the solvent to evaporate in about 70% yield.

Refinement top

Carbon-bound H-atoms were placed in calculated positions (C—H 0.95 to 0.99 Å) and were included in the refinement in the riding model approximation, with U(H) set to 1.2Ueq(C).The chlorine atom of the phenylene ring is disordered over two rings; the C–Cl distances were restrained to 1.75±0.01 Å. The disorder refined to a 0.81:0.19 ratio. The two chlorodifluoromethyl groups of the chlorodifluoroacetate anion are both disordered. Distance restraints were applied: C–C distances = 1.50±0.01 Å, C–Cl 1.75±0.01 Å; C–F 1.35±0.01 Å; Cl···F 2.52±0.01 Å and F···F 2.21±0.01 Å. Additionally, the six halogen atoms of each anion were restrained to lie in an approximate plane, the atoms being allowed to deviate by a maximum of 0.05 Å. The anisotropic temperature factors of the disordered atoms were restrained to be nearly isotropic. The final difference Fourier map had a large peak/hole (-1.76 e Å3 in the vicinity of one of the two disordered anions.

Computing details top

Data collection: APEX2 (Bruker, 2007); cell refinement: SAINT (Bruker, 2007); data reduction: SAINT (Bruker, 2007); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: X-SEED (Barbour, 2001); software used to prepare material for publication: publCIF (Westrip, 2008).

Figures top
[Figure 1] Fig. 1. 70% Probability thermal ellipsoid plot (Barbour, 2001) of the [Ag(C26H24P2)2] cation. Hydrogen atoms are drawn as spheres of arbitrary radii.
[Figure 2] Fig. 2. 70% Probability thermal ellipsoid plot (Barbour, 2001) of the [Sn(ClC6H4)(C6H5)2(C2ClF2O2)] anion. The disordered atoms are not shown. Hydrogen atoms are drawn as spheres of arbitrary radii.
Bis[1,2-bis(diphenylphosphino)ethane-κ2P:P']silver(I) bis(chlorodifluoroacetato-κO)(4-chlorophenyl)diphenylstannate(IV) top
Crystal data top
[Ag(C26H24P2)2][Sn(C2ClF2O2)2(C6H5)2(C6H4Cl)]Z = 2
Mr = 1548.03F000 = 1564
Triclinic, P1Dx = 1.505 Mg m−3
Hall symbol: -P 1Mo Kα radiation
λ = 0.71073 Å
a = 13.4774 (3) ÅCell parameters from 3393 reflections
b = 15.4957 (5) Åθ = 2.3–21.7º
c = 18.1475 (4) ŵ = 0.92 mm−1
α = 69.674 (2)ºT = 100 (2) K
β = 84.646 (2)ºBlock, colorless
γ = 74.030 (2)º0.19 × 0.09 × 0.06 mm
V = 3416.8 (2) Å3
Data collection top
Bruker SMART APEX
diffractometer		16111 independent reflections
Radiation source: fine-focus sealed tube10301 reflections with I > 2σ(I)
Monochromator: graphiteRint = 0.076
T = 100(2) Kθmax = 27.5º
ω scansθmin = 1.2º
Absorption correction: Multi-scan
SADABS (Sheldrick, 1996)		h = −17→17
Tmin = 0.844, Tmax = 0.947k = −20→15
37182 measured reflectionsl = −23→23
Refinement top
Refinement on F2Secondary atom site location: difference Fourier map
Least-squares matrix: fullHydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.057H-atom parameters constrained
wR(F2) = 0.148  w = 1/[σ2(Fo2) + (0.0516P)2 + 3.4764P]
where P = (Fo2 + 2Fc2)/3
S = 1.01(Δ/σ)max = 0.001
16111 reflectionsΔρmax = 1.36 e Å−3
868 parametersΔρmin = −1.76 e Å−3
118 restraintsExtinction correction: none
Primary atom site location: structure-invariant direct methods
Crystal data top
[Ag(C26H24P2)2][Sn(C2ClF2O2)2(C6H5)2(C6H4Cl)]γ = 74.030 (2)º
Mr = 1548.03V = 3416.8 (2) Å3
Triclinic, P1Z = 2
a = 13.4774 (3) ÅMo Kα
b = 15.4957 (5) ŵ = 0.92 mm−1
c = 18.1475 (4) ÅT = 100 (2) K
α = 69.674 (2)º0.19 × 0.09 × 0.06 mm
β = 84.646 (2)º
Data collection top
Bruker SMART APEX
diffractometer		16111 independent reflections
Absorption correction: Multi-scan
SADABS (Sheldrick, 1996)		10301 reflections with I > 2σ(I)
Tmin = 0.844, Tmax = 0.947Rint = 0.076
37182 measured reflections
Refinement top
R[F2 > 2σ(F2)] = 0.057118 restraints
wR(F2) = 0.148H-atom parameters constrained
S = 1.01Δρmax = 1.36 e Å−3
16111 reflectionsΔρmin = −1.76 e Å−3
868 parameters
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/UeqOcc. (<1)
Sn10.18356 (3)0.41136 (3)0.74160 (2)0.02029 (10)
Ag10.34144 (3)−0.12991 (3)0.74626 (2)0.01634 (10)
Cl1−0.16052 (14)0.15843 (14)0.80533 (11)0.0334 (5)0.813 (4)
Cl20.13197 (16)0.43648 (19)1.02140 (12)0.0509 (7)0.813 (4)
Cl30.1026 (3)0.4097 (2)0.45258 (17)0.0712 (12)0.722 (5)
F10.3254 (3)0.3662 (3)1.02756 (19)0.0261 (11)0.813 (4)
F20.2350 (4)0.2721 (3)1.0236 (2)0.0530 (14)0.813 (4)
F30.1652 (5)0.5441 (3)0.4608 (3)0.0505 (17)0.722 (5)
F40.2835 (4)0.4236 (5)0.4476 (3)0.077 (3)0.722 (5)
Cl2'0.2959 (8)0.2388 (5)1.0223 (4)0.0530 (14)0.19
Cl3'0.2789 (5)0.5165 (6)0.4514 (3)0.059 (3)0.278 (5)
F1'0.2994 (11)0.3969 (9)1.0274 (5)0.0261 (11)0.19
F2'0.1466 (7)0.3712 (11)1.0226 (5)0.0509 (7)0.19
F3'0.0957 (6)0.5099 (9)0.4631 (5)0.074 (5)0.278 (5)
F4'0.2082 (12)0.3847 (7)0.4476 (5)0.071 (5)0.278 (5)
P10.43266 (10)−0.27742 (10)0.71408 (7)0.0162 (3)
P20.26737 (10)−0.24426 (10)0.85526 (7)0.0157 (3)
P30.40448 (10)−0.00758 (10)0.77467 (7)0.0170 (3)
P40.22324 (10)0.01273 (10)0.65085 (7)0.0170 (3)
O10.1970 (3)0.3585 (3)0.8728 (2)0.0250 (9)
O20.2980 (3)0.4534 (3)0.8737 (2)0.0236 (8)
O30.1653 (3)0.4574 (3)0.6122 (2)0.0249 (9)
O40.2539 (3)0.3173 (3)0.5987 (2)0.0342 (10)
C10.0862 (4)0.3184 (4)0.7596 (3)0.0210 (12)
C20.0951 (4)0.2341 (4)0.8233 (3)0.0231 (12)
H20.15250.21160.85790.028*
C30.0214 (5)0.1825 (4)0.8372 (3)0.0287 (13)
H30.02910.12440.88000.034*
C4−0.0633 (4)0.2173 (4)0.7876 (3)0.0290 (13)
H4−0.11560.18410.79800.035*0.187 (4)
C5−0.0729 (5)0.2994 (5)0.7231 (4)0.0351 (15)
H5−0.12990.32130.68830.042*
C60.0012 (4)0.3493 (4)0.7100 (3)0.0298 (14)
H6−0.00590.40620.66600.036*
C70.3472 (4)0.3784 (4)0.7282 (3)0.0260 (13)
C80.4138 (5)0.3012 (4)0.7814 (3)0.0297 (14)
H80.38610.25870.82420.036*
C90.5190 (5)0.2854 (5)0.7730 (4)0.0380 (17)
H90.56370.23120.80850.046*
C100.5589 (5)0.3497 (5)0.7120 (4)0.0391 (17)
H100.63160.34070.70760.047*0.813 (4)
Cl1'0.6905 (9)0.3299 (19)0.7021 (15)0.171 (10)0.187 (4)
C110.4963 (5)0.4253 (5)0.6585 (4)0.0346 (15)
H110.52510.46740.61600.042*
C120.3899 (5)0.4407 (5)0.6663 (3)0.0304 (14)
H120.34590.49390.62930.036*
C130.0986 (4)0.5528 (4)0.7339 (3)0.0202 (11)
C140.0815 (5)0.6263 (4)0.6624 (3)0.0287 (13)
H140.10890.61380.61590.034*
C150.0251 (5)0.7179 (4)0.6573 (4)0.0337 (15)
H150.01410.76690.60750.040*
C16−0.0152 (4)0.7388 (4)0.7241 (3)0.0313 (14)
H16−0.05270.80170.72060.038*
C170.0001 (4)0.6661 (4)0.7957 (3)0.0274 (13)
H17−0.02770.67900.84200.033*
C180.0561 (4)0.5738 (4)0.8008 (3)0.0249 (12)
H180.06550.52460.85060.030*
C190.2499 (4)0.3938 (4)0.9047 (3)0.0210 (12)
C200.2436 (4)0.3606 (4)0.9940 (3)0.0322 (14)
C210.2060 (4)0.4013 (4)0.5744 (3)0.0254 (13)
C220.1933 (4)0.4485 (4)0.4850 (3)0.0371 (16)
C230.4185 (4)−0.2828 (4)0.6172 (3)0.0194 (11)
C240.4972 (4)−0.2732 (4)0.5614 (3)0.0277 (13)
H240.5598−0.26440.57380.033*
C250.4830 (6)−0.2766 (5)0.4875 (3)0.0388 (17)
H250.5367−0.27090.44970.047*
C270.3918 (6)−0.2882 (5)0.4686 (3)0.045 (2)
H270.3831−0.29070.41810.054*
C280.3134 (5)−0.2961 (5)0.5227 (3)0.0406 (17)
H280.2507−0.30420.50950.049*
C290.3258 (5)−0.2922 (4)0.5963 (3)0.0286 (13)
H290.2707−0.29600.63300.034*
C300.5692 (4)−0.3352 (4)0.7361 (3)0.0180 (11)
C310.6268 (4)−0.2935 (4)0.7664 (3)0.0205 (11)
H310.5951−0.23470.77450.025*
C320.7299 (4)−0.3368 (5)0.7848 (3)0.0300 (14)
H320.7692−0.30730.80480.036*
C330.7756 (4)−0.4231 (5)0.7742 (3)0.0338 (15)
H330.8464−0.45300.78700.041*
C340.7198 (4)−0.4656 (5)0.7454 (3)0.0327 (15)
H340.7518−0.52500.73830.039*
C350.6161 (4)−0.4223 (4)0.7264 (3)0.0234 (12)
H350.5773−0.45230.70670.028*
C360.3707 (4)−0.3694 (4)0.7792 (3)0.0158 (10)
H36A0.3654−0.41190.75060.019*
H36B0.4160−0.40860.82530.019*
C370.2626 (4)−0.3305 (4)0.8087 (3)0.0178 (11)
H37A0.2381−0.38360.84710.021*
H37B0.2135−0.29940.76410.021*
C380.1386 (4)−0.2200 (4)0.8980 (3)0.0187 (11)
C390.0693 (4)−0.1315 (4)0.8647 (3)0.0233 (12)
H390.0888−0.08560.81970.028*
C40−0.0283 (4)−0.1102 (5)0.8972 (3)0.0309 (14)
H40−0.0753−0.04970.87470.037*
C41−0.0561 (4)−0.1777 (5)0.9623 (3)0.0295 (14)
H41−0.1228−0.16340.98430.035*
C420.0110 (4)−0.2650 (5)0.9956 (3)0.0314 (14)
H42−0.0093−0.31091.04030.038*
C430.1082 (4)−0.2862 (4)0.9639 (3)0.0246 (13)
H430.1548−0.34670.98740.030*
C440.3491 (4)−0.3121 (4)0.9418 (3)0.0193 (11)
C450.3547 (4)−0.4080 (4)0.9852 (3)0.0197 (11)
H450.3225−0.44320.96580.024*
C460.4067 (4)−0.4511 (4)1.0557 (3)0.0254 (13)
H460.4099−0.51591.08500.031*
C470.4545 (4)−0.4003 (4)1.0844 (3)0.0273 (13)
H470.4880−0.42961.13410.033*
C480.4532 (5)−0.3073 (4)1.0405 (3)0.0301 (14)
H480.4882−0.27331.05900.036*
C490.4007 (4)−0.2631 (4)0.9691 (3)0.0209 (12)
H490.4003−0.19920.93900.025*
C500.3564 (4)0.0103 (4)0.8679 (3)0.0183 (11)
C510.2711 (4)−0.0222 (4)0.9024 (3)0.0238 (12)
H510.2355−0.04770.87570.029*
C520.2381 (5)−0.0172 (4)0.9757 (3)0.0312 (14)
H520.1807−0.04070.99970.037*
C530.2886 (5)0.0219 (5)1.0147 (3)0.0371 (17)
H530.26600.02521.06510.044*
C540.3704 (5)0.0554 (5)0.9797 (3)0.0355 (16)
H540.40470.08221.00610.043*
C550.4055 (4)0.0513 (4)0.9055 (3)0.0278 (13)
H550.46200.07630.88130.033*
C560.5389 (4)−0.0037 (4)0.7712 (3)0.0170 (11)
C570.5746 (4)0.0730 (4)0.7224 (3)0.0242 (12)
H570.52680.12910.69190.029*
C580.6785 (4)0.0689 (4)0.7176 (3)0.0268 (13)
H580.70160.12230.68470.032*
C590.7492 (4)−0.0138 (4)0.7611 (3)0.0227 (12)
H590.8211−0.01790.75610.027*
C600.7153 (4)−0.0889 (4)0.8112 (3)0.0228 (12)
H600.7639−0.14390.84230.027*
C610.6111 (4)−0.0863 (4)0.8173 (3)0.0213 (12)
H610.5885−0.13920.85190.026*
C620.3403 (4)0.1056 (4)0.7001 (3)0.0213 (12)
H62A0.34060.15910.71780.026*
H62B0.37950.11320.65030.026*
C630.2292 (4)0.1095 (4)0.6854 (3)0.0210 (11)
H63A0.19730.17160.64560.025*
H63B0.18930.10460.73460.025*
C640.0860 (4)0.0357 (4)0.6307 (3)0.0192 (11)
C650.0534 (4)−0.0335 (4)0.6162 (3)0.0298 (14)
H650.1001−0.09410.62280.036*
C66−0.0472 (5)−0.0158 (5)0.5919 (3)0.0333 (14)
H66−0.0682−0.06360.58070.040*
C67−0.1161 (4)0.0700 (5)0.5841 (3)0.0304 (14)
H67−0.18450.08270.56650.037*
C68−0.0852 (5)0.1373 (5)0.6019 (4)0.0394 (16)
H68−0.13350.19630.59830.047*
C690.0162 (5)0.1213 (5)0.6254 (4)0.0375 (16)
H690.03650.16890.63740.045*
C700.2744 (4)0.0472 (4)0.5509 (3)0.0189 (11)
C710.3469 (5)−0.0209 (4)0.5279 (3)0.0289 (14)
H710.3717−0.08310.56470.035*
C720.3835 (5)0.0010 (5)0.4515 (3)0.0395 (17)
H720.4336−0.04610.43600.047*
C730.3481 (5)0.0902 (5)0.3983 (3)0.0346 (15)
H730.37290.10480.34580.042*
C740.2759 (5)0.1593 (5)0.4209 (3)0.0384 (16)
H740.25200.22170.38420.046*
C750.2390 (5)0.1371 (4)0.4968 (3)0.0324 (15)
H750.18870.18420.51210.039*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Sn10.0262 (2)0.0174 (2)0.01686 (18)−0.00631 (16)−0.00245 (14)−0.00419 (15)
Ag10.0203 (2)0.0146 (2)0.01421 (18)−0.00492 (16)0.00009 (14)−0.00477 (15)
Cl10.0331 (10)0.0287 (11)0.0412 (11)−0.0200 (9)−0.0059 (8)−0.0043 (8)
Cl20.0482 (13)0.0701 (18)0.0350 (11)−0.0151 (12)0.0073 (9)−0.0204 (11)
Cl30.100 (3)0.0479 (19)0.0606 (18)−0.0052 (17)−0.0476 (17)−0.0114 (14)
F10.028 (2)0.028 (3)0.0202 (16)−0.005 (2)−0.0082 (15)−0.0055 (16)
F20.066 (4)0.043 (3)0.043 (2)−0.018 (3)−0.014 (3)0.001 (2)
F30.086 (4)0.035 (3)0.025 (3)−0.022 (3)−0.011 (3)0.004 (2)
F40.059 (4)0.111 (6)0.024 (3)0.016 (4)0.010 (3)−0.009 (3)
Cl2'0.066 (4)0.043 (3)0.043 (2)−0.018 (3)−0.014 (3)0.001 (2)
Cl3'0.066 (5)0.073 (5)0.037 (3)−0.033 (4)0.015 (3)−0.010 (3)
F1'0.028 (2)0.028 (3)0.0202 (16)−0.005 (2)−0.0082 (15)−0.0055 (16)
F2'0.0482 (13)0.0701 (18)0.0350 (11)−0.0151 (12)0.0073 (9)−0.0204 (11)
F3'0.077 (9)0.089 (10)0.045 (7)−0.018 (8)−0.024 (7)−0.004 (7)
F4'0.096 (10)0.076 (9)0.058 (8)−0.036 (8)−0.007 (7)−0.030 (7)
P10.0172 (7)0.0170 (7)0.0140 (6)−0.0032 (6)−0.0009 (5)−0.0056 (5)
P20.0164 (6)0.0152 (7)0.0145 (6)−0.0049 (5)0.0002 (5)−0.0033 (5)
P30.0220 (7)0.0161 (7)0.0131 (6)−0.0056 (6)−0.0007 (5)−0.0046 (5)
P40.0192 (7)0.0164 (7)0.0156 (6)−0.0049 (6)−0.0015 (5)−0.0049 (5)
O10.033 (2)0.028 (2)0.0170 (18)−0.0128 (19)−0.0060 (15)−0.0059 (16)
O20.028 (2)0.019 (2)0.0230 (19)−0.0091 (17)−0.0015 (16)−0.0025 (16)
O30.032 (2)0.024 (2)0.0184 (18)−0.0064 (18)−0.0020 (16)−0.0073 (17)
O40.053 (3)0.017 (2)0.029 (2)−0.004 (2)−0.0024 (19)−0.0054 (18)
C10.026 (3)0.021 (3)0.019 (3)−0.009 (2)0.002 (2)−0.009 (2)
C20.027 (3)0.025 (3)0.017 (3)−0.007 (3)0.000 (2)−0.008 (2)
C30.040 (4)0.025 (3)0.022 (3)−0.017 (3)−0.002 (2)−0.002 (2)
C40.032 (3)0.031 (4)0.030 (3)−0.017 (3)0.000 (2)−0.010 (3)
C50.035 (3)0.035 (4)0.035 (3)−0.012 (3)−0.009 (3)−0.007 (3)
C60.030 (3)0.029 (4)0.027 (3)−0.008 (3)−0.004 (2)−0.004 (3)
C70.029 (3)0.026 (3)0.028 (3)−0.005 (3)−0.005 (2)−0.017 (3)
C80.034 (3)0.026 (3)0.028 (3)−0.002 (3)−0.007 (2)−0.011 (3)
C90.033 (4)0.041 (4)0.046 (4)0.009 (3)−0.014 (3)−0.032 (3)
C100.030 (3)0.060 (5)0.047 (4)−0.014 (3)0.008 (3)−0.041 (4)
Cl1'0.168 (13)0.177 (13)0.183 (12)−0.050 (9)−0.007 (9)−0.074 (9)
C110.036 (4)0.048 (4)0.039 (4)−0.021 (3)0.008 (3)−0.032 (3)
C120.034 (3)0.029 (4)0.034 (3)−0.008 (3)0.002 (3)−0.019 (3)
C130.020 (3)0.023 (3)0.020 (3)−0.009 (2)−0.001 (2)−0.007 (2)
C140.037 (3)0.023 (3)0.025 (3)−0.006 (3)0.002 (2)−0.008 (2)
C150.039 (4)0.019 (3)0.036 (3)−0.006 (3)−0.004 (3)−0.003 (3)
C160.024 (3)0.023 (3)0.044 (4)0.001 (3)−0.004 (3)−0.012 (3)
C170.019 (3)0.031 (4)0.038 (3)−0.005 (3)0.002 (2)−0.019 (3)
C180.018 (3)0.030 (3)0.027 (3)−0.007 (3)−0.002 (2)−0.010 (3)
C190.021 (3)0.022 (3)0.018 (3)−0.002 (2)−0.004 (2)−0.006 (2)
C200.043 (4)0.034 (4)0.024 (3)−0.021 (3)−0.009 (3)−0.004 (3)
C210.035 (3)0.028 (3)0.017 (3)−0.016 (3)0.000 (2)−0.006 (2)
C220.044 (4)0.038 (4)0.021 (3)−0.002 (3)−0.001 (3)−0.007 (3)
C230.026 (3)0.012 (3)0.015 (2)0.005 (2)−0.004 (2)−0.003 (2)
C240.030 (3)0.025 (3)0.024 (3)−0.001 (3)0.005 (2)−0.008 (2)
C250.060 (5)0.026 (4)0.015 (3)0.007 (3)0.004 (3)−0.004 (3)
C270.083 (6)0.026 (4)0.019 (3)0.010 (4)−0.020 (3)−0.011 (3)
C280.054 (4)0.040 (4)0.026 (3)−0.006 (3)−0.018 (3)−0.009 (3)
C290.032 (3)0.026 (3)0.027 (3)−0.005 (3)−0.008 (2)−0.008 (3)
C300.017 (3)0.022 (3)0.014 (2)−0.006 (2)0.0019 (19)−0.004 (2)
C310.018 (3)0.022 (3)0.022 (3)−0.007 (2)−0.002 (2)−0.007 (2)
C320.023 (3)0.045 (4)0.023 (3)−0.017 (3)−0.003 (2)−0.006 (3)
C330.016 (3)0.045 (4)0.032 (3)−0.002 (3)0.002 (2)−0.008 (3)
C340.027 (3)0.037 (4)0.030 (3)0.002 (3)0.002 (2)−0.016 (3)
C350.021 (3)0.026 (3)0.026 (3)−0.001 (2)−0.004 (2)−0.015 (2)
C360.018 (3)0.011 (3)0.019 (2)−0.005 (2)−0.0043 (19)−0.003 (2)
C370.019 (3)0.017 (3)0.017 (2)−0.004 (2)−0.003 (2)−0.006 (2)
C380.017 (3)0.020 (3)0.020 (3)−0.003 (2)−0.003 (2)−0.009 (2)
C390.018 (3)0.027 (3)0.021 (3)−0.002 (2)−0.002 (2)−0.005 (2)
C400.022 (3)0.034 (4)0.037 (3)−0.001 (3)−0.004 (2)−0.017 (3)
C410.019 (3)0.040 (4)0.032 (3)−0.003 (3)0.004 (2)−0.020 (3)
C420.028 (3)0.042 (4)0.024 (3)−0.008 (3)0.008 (2)−0.014 (3)
C430.024 (3)0.022 (3)0.022 (3)0.000 (2)0.004 (2)−0.006 (2)
C440.020 (3)0.018 (3)0.015 (2)−0.003 (2)0.002 (2)−0.002 (2)
C450.021 (3)0.018 (3)0.020 (3)−0.004 (2)0.003 (2)−0.008 (2)
C460.033 (3)0.020 (3)0.020 (3)−0.003 (3)−0.003 (2)−0.004 (2)
C470.028 (3)0.029 (3)0.023 (3)0.001 (3)−0.004 (2)−0.012 (3)
C480.034 (3)0.030 (4)0.027 (3)−0.008 (3)−0.007 (2)−0.010 (3)
C490.018 (3)0.028 (3)0.020 (3)−0.009 (2)−0.002 (2)−0.009 (2)
C500.021 (3)0.013 (3)0.019 (2)0.002 (2)−0.004 (2)−0.007 (2)
C510.028 (3)0.024 (3)0.021 (3)−0.004 (3)0.000 (2)−0.011 (2)
C520.033 (3)0.031 (4)0.025 (3)−0.003 (3)0.007 (2)−0.010 (3)
C530.035 (4)0.047 (4)0.021 (3)0.012 (3)−0.006 (3)−0.018 (3)
C540.033 (3)0.048 (4)0.032 (3)0.005 (3)−0.010 (3)−0.032 (3)
C550.028 (3)0.032 (4)0.027 (3)−0.004 (3)−0.005 (2)−0.016 (3)
C560.024 (3)0.017 (3)0.015 (2)−0.008 (2)−0.001 (2)−0.011 (2)
C570.032 (3)0.019 (3)0.020 (3)−0.005 (3)0.001 (2)−0.006 (2)
C580.031 (3)0.025 (3)0.027 (3)−0.014 (3)0.000 (2)−0.006 (3)
C590.024 (3)0.029 (3)0.024 (3)−0.013 (3)0.001 (2)−0.014 (2)
C600.031 (3)0.019 (3)0.017 (3)−0.004 (2)−0.005 (2)−0.004 (2)
C610.027 (3)0.024 (3)0.017 (2)−0.012 (2)−0.001 (2)−0.006 (2)
C620.029 (3)0.016 (3)0.018 (3)−0.004 (2)−0.007 (2)−0.004 (2)
C630.025 (3)0.015 (3)0.023 (3)−0.004 (2)−0.003 (2)−0.008 (2)
C640.019 (3)0.021 (3)0.016 (2)−0.003 (2)0.000 (2)−0.006 (2)
C650.026 (3)0.019 (3)0.039 (3)0.000 (3)−0.010 (3)−0.005 (3)
C660.032 (3)0.035 (4)0.037 (3)−0.012 (3)−0.009 (3)−0.013 (3)
C670.020 (3)0.038 (4)0.033 (3)−0.008 (3)−0.001 (2)−0.011 (3)
C680.022 (3)0.037 (4)0.059 (4)0.005 (3)−0.008 (3)−0.024 (3)
C690.031 (3)0.034 (4)0.055 (4)−0.004 (3)−0.008 (3)−0.025 (3)
C700.021 (3)0.023 (3)0.013 (2)−0.008 (2)0.0004 (19)−0.003 (2)
C710.045 (4)0.016 (3)0.019 (3)−0.005 (3)0.003 (2)−0.001 (2)
C720.057 (4)0.026 (4)0.030 (3)−0.004 (3)0.012 (3)−0.011 (3)
C730.054 (4)0.037 (4)0.015 (3)−0.020 (3)0.009 (3)−0.007 (3)
C740.051 (4)0.032 (4)0.022 (3)−0.008 (3)0.004 (3)−0.001 (3)
C750.033 (3)0.027 (4)0.022 (3)0.004 (3)0.006 (2)0.000 (3)
Geometric parameters (Å, °) top
Sn1—C12.131 (6)C30—C351.389 (7)
Sn1—C72.133 (6)C31—C321.382 (7)
Sn1—C132.138 (5)C31—H310.9500
Sn1—O12.239 (3)C32—C331.382 (9)
Sn1—O32.221 (3)C32—H320.9500
Ag1—P12.515 (1)C33—C341.363 (9)
Ag1—P22.494 (1)C33—H330.9500
Ag1—P32.495 (2)C34—C351.391 (7)
Ag1—P42.518 (1)C34—H340.9500
Cl1—C41.740 (5)C35—H350.9500
Cl2—C201.785 (5)C36—C371.539 (7)
Cl3—C221.728 (6)C36—H36A0.9900
F1—C201.345 (6)C36—H36B0.9900
F2—C201.322 (6)C37—H37A0.9900
F3—C221.343 (6)C37—H37B0.9900
F4—C221.363 (6)C38—C431.392 (7)
Cl2'—C201.728 (7)C38—C391.394 (7)
Cl3'—C221.704 (7)C39—C401.392 (7)
F1'—C201.343 (8)C39—H390.9500
F2'—C201.349 (8)C40—C411.381 (8)
F3'—C221.393 (8)C40—H400.9500
F4'—C221.345 (8)C41—C421.369 (8)
P1—C231.819 (5)C41—H410.9500
P1—C301.825 (5)C42—C431.381 (7)
P1—C361.851 (5)C42—H420.9500
P2—C441.823 (5)C43—H430.9500
P2—C371.828 (5)C44—C491.387 (7)
P2—C381.829 (5)C44—C451.403 (7)
P3—C561.824 (5)C45—C461.375 (7)
P3—C501.839 (5)C45—H450.9500
P3—C621.841 (5)C46—C471.389 (8)
P4—C701.829 (5)C46—H460.9500
P4—C641.832 (5)C47—C481.380 (8)
P4—C631.838 (5)C47—H470.9500
O1—C191.286 (6)C48—C491.390 (7)
O2—C191.221 (6)C48—H480.9500
O3—C211.267 (7)C49—H490.9500
O4—C211.224 (7)C50—C551.387 (8)
C1—C61.394 (7)C50—C511.390 (7)
C1—C21.395 (7)C51—C521.384 (7)
C2—C31.393 (8)C51—H510.9500
C2—H20.9500C52—C531.395 (9)
C3—C41.386 (8)C52—H520.9500
C3—H30.9500C53—C541.357 (9)
C4—C51.382 (8)C53—H530.9500
C4—H40.9500C54—C551.401 (7)
C5—C61.379 (8)C54—H540.9500
C5—H50.9500C55—H550.9500
C6—H60.9500C56—C571.390 (7)
C7—C81.392 (8)C56—C611.416 (7)
C7—C121.400 (8)C57—C581.379 (8)
C8—C91.373 (8)C57—H570.9500
C8—H80.9500C58—C591.393 (8)
C9—C101.388 (10)C58—H580.9500
C9—H90.9500C59—C601.368 (8)
C10—C111.359 (9)C59—H590.9500
C10—Cl1'1.718 (10)C60—C611.390 (7)
C10—H100.9500C60—H600.9500
C11—C121.389 (8)C61—H610.9500
C11—H110.9500C62—C631.526 (7)
C12—H120.9500C62—H62A0.9900
C13—C141.384 (7)C62—H62B0.9900
C13—C181.397 (7)C63—H63A0.9900
C14—C151.390 (8)C63—H63B0.9900
C14—H140.9500C64—C651.376 (8)
C15—C161.386 (8)C64—C691.376 (8)
C15—H150.9500C65—C661.389 (8)
C16—C171.380 (8)C65—H650.9500
C16—H160.9500C66—C671.365 (8)
C17—C181.397 (8)C66—H660.9500
C17—H170.9500C67—C681.366 (9)
C18—H180.9500C67—H670.9500
C19—C201.523 (6)C68—C691.398 (8)
C21—C221.534 (6)C68—H680.9500
C23—C241.397 (7)C69—H690.9500
C23—C291.397 (8)C70—C751.379 (8)
C24—C251.394 (8)C70—C711.380 (7)
C24—H240.9500C71—C721.387 (7)
C25—C271.379 (10)C71—H710.9500
C25—H250.9500C72—C731.366 (8)
C27—C281.373 (9)C72—H720.9500
C27—H270.9500C73—C741.385 (9)
C28—C291.386 (8)C73—H730.9500
C28—H280.9500C74—C751.380 (7)
C29—H290.9500C74—H740.9500
C30—C311.386 (7)C75—H750.9500
C1—Sn1—C7127.5 (2)C31—C30—P1119.6 (4)
C1—Sn1—C13112.4 (2)C35—C30—P1121.4 (4)
C1—Sn1—O391.1 (2)C32—C31—C30120.6 (5)
C1—Sn1—O185.5 (2)C32—C31—H31119.7
C7—Sn1—O191.8 (2)C30—C31—H31119.7
C7—Sn1—C13120.1 (2)C33—C32—C31119.7 (6)
C7—Sn1—O389.9 (2)C33—C32—H32120.1
C13—Sn1—O387.2 (2)C31—C32—H32120.1
C13—Sn1—O194.5 (2)C34—C33—C32120.5 (6)
O1—Sn1—O3176.6 (1)C34—C33—H33119.8
P1—Ag1—P282.98 (4)C32—C33—H33119.8
P1—Ag1—P3132.80 (5)C33—C34—C35120.1 (6)
P1—Ag1—P4122.85 (4)C33—C34—H34119.9
P2—Ag1—P3119.12 (4)C35—C34—H34119.9
P2—Ag1—P4119.90 (4)C30—C35—C34120.1 (6)
P3—Ag1—P483.87 (5)C30—C35—H35119.9
C23—P1—C30103.0 (2)C34—C35—H35119.9
C23—P1—C36103.0 (2)C37—C36—P1115.0 (4)
C30—P1—C36101.9 (2)C37—C36—H36A108.5
C23—P1—Ag1120.14 (17)P1—C36—H36A108.5
C30—P1—Ag1121.86 (18)C37—C36—H36B108.5
C36—P1—Ag1103.86 (16)P1—C36—H36B108.5
C44—P2—C37105.6 (2)H36A—C36—H36B107.5
C44—P2—C38102.5 (2)C36—C37—P2109.8 (3)
C37—P2—C38103.0 (2)C36—C37—H37A109.7
C44—P2—Ag1115.96 (17)P2—C37—H37A109.7
C37—P2—Ag1100.48 (16)C36—C37—H37B109.7
C38—P2—Ag1126.80 (18)P2—C37—H37B109.7
C56—P3—C50104.1 (2)H37A—C37—H37B108.2
C56—P3—C62103.9 (2)C43—C38—C39118.7 (5)
C50—P3—C62103.3 (2)C43—C38—P2122.2 (4)
C56—P3—Ag1125.32 (17)C39—C38—P2119.0 (4)
C50—P3—Ag1113.64 (18)C40—C39—C38120.3 (5)
C62—P3—Ag1104.17 (18)C40—C39—H39119.8
C70—P4—C64100.8 (2)C38—C39—H39119.8
C70—P4—C63103.5 (3)C41—C40—C39119.4 (6)
C64—P4—C63104.2 (2)C41—C40—H40120.3
C70—P4—Ag1113.72 (17)C39—C40—H40120.3
C64—P4—Ag1129.67 (18)C42—C41—C40121.0 (5)
C63—P4—Ag1102.04 (17)C42—C41—H41119.5
C19—O1—Sn1118.7 (3)C40—C41—H41119.5
C21—O3—Sn1121.1 (3)C41—C42—C43119.7 (6)
C6—C1—C2117.9 (5)C41—C42—H42120.1
C6—C1—Sn1117.7 (4)C43—C42—H42120.1
C2—C1—Sn1123.9 (4)C42—C43—C38120.8 (5)
C3—C2—C1121.1 (5)C42—C43—H43119.6
C3—C2—H2119.4C38—C43—H43119.6
C1—C2—H2119.4C49—C44—C45119.1 (5)
C4—C3—C2119.0 (5)C49—C44—P2117.4 (4)
C4—C3—H3120.5C45—C44—P2123.3 (4)
C2—C3—H3120.5C46—C45—C44120.2 (5)
C5—C4—C3121.0 (5)C46—C45—H45119.9
C5—C4—Cl1118.4 (5)C44—C45—H45119.9
C3—C4—Cl1120.6 (4)C45—C46—C47120.4 (5)
C5—C4—H4119.5C45—C46—H46119.8
C3—C4—H4119.5C47—C46—H46119.8
C6—C5—C4119.2 (6)C48—C47—C46119.8 (5)
C6—C5—H5120.4C48—C47—H47120.1
C4—C5—H5120.4C46—C47—H47120.1
C5—C6—C1121.7 (6)C47—C48—C49120.2 (6)
C5—C6—H6119.1C47—C48—H48119.9
C1—C6—H6119.1C49—C48—H48119.9
C8—C7—C12118.3 (5)C44—C49—C48120.3 (5)
C8—C7—Sn1122.9 (4)C44—C49—H49119.9
C12—C7—Sn1118.6 (4)C48—C49—H49119.9
C9—C8—C7121.1 (6)C55—C50—C51119.9 (5)
C9—C8—H8119.4C55—C50—P3121.7 (4)
C7—C8—H8119.4C51—C50—P3118.3 (4)
C8—C9—C10119.1 (6)C52—C51—C50119.8 (5)
C8—C9—H9120.4C52—C51—H51120.1
C10—C9—H9120.4C50—C51—H51120.1
C11—C10—C9121.4 (6)C51—C52—C53120.5 (6)
C11—C10—Cl1'119.6 (11)C51—C52—H52119.7
C9—C10—Cl1'118.9 (11)C53—C52—H52119.7
C11—C10—H10119.3C54—C53—C52119.1 (5)
C9—C10—H10119.3C54—C53—H53120.4
C10—C11—C12119.5 (6)C52—C53—H53120.4
C10—C11—H11120.3C53—C54—C55121.6 (6)
C12—C11—H11120.3C53—C54—H54119.2
C11—C12—C7120.5 (6)C55—C54—H54119.2
C11—C12—H12119.8C50—C55—C54118.9 (6)
C7—C12—H12119.8C50—C55—H55120.6
C14—C13—C18117.6 (5)C54—C55—H55120.6
C14—C13—Sn1121.4 (4)C57—C56—C61118.8 (5)
C18—C13—Sn1121.0 (4)C57—C56—P3123.6 (4)
C13—C14—C15121.4 (5)C61—C56—P3117.5 (4)
C13—C14—H14119.3C58—C57—C56121.1 (5)
C15—C14—H14119.3C58—C57—H57119.5
C16—C15—C14120.8 (6)C56—C57—H57119.5
C16—C15—H15119.6C57—C58—C59119.7 (5)
C14—C15—H15119.6C57—C58—H58120.1
C17—C16—C15118.6 (6)C59—C58—H58120.1
C17—C16—H16120.7C60—C59—C58120.0 (5)
C15—C16—H16120.7C60—C59—H59120.0
C16—C17—C18120.7 (5)C58—C59—H59120.0
C16—C17—H17119.7C59—C60—C61121.2 (5)
C18—C17—H17119.7C59—C60—H60119.4
C17—C18—C13121.0 (5)C61—C60—H60119.4
C17—C18—H18119.5C60—C61—C56119.1 (5)
C13—C18—H18119.5C60—C61—H61120.4
O2—C19—O1129.4 (5)C56—C61—H61120.4
O2—C19—C20116.6 (5)C63—C62—P3111.8 (4)
O1—C19—C20113.8 (5)C63—C62—H62A109.2
F2—C20—F1108.5 (4)P3—C62—H62A109.2
F1'—C20—F2'110.9 (7)C63—C62—H62B109.2
F2—C20—C19111.7 (4)P3—C62—H62B109.2
F1'—C20—C19113.9 (6)H62A—C62—H62B107.9
F1—C20—C19112.8 (4)C62—C63—P4111.5 (4)
F2'—C20—C19114.3 (6)C62—C63—H63A109.3
F1'—C20—Cl2'108.2 (6)P4—C63—H63A109.3
F2'—C20—Cl2'104.7 (6)C62—C63—H63B109.3
C19—C20—Cl2'103.9 (4)P4—C63—H63B109.3
F2—C20—Cl2108.3 (4)H63A—C63—H63B108.0
F1—C20—Cl2107.1 (4)C65—C64—C69119.2 (5)
C19—C20—Cl2108.4 (3)C65—C64—P4118.3 (4)
O4—C21—O3129.7 (5)C69—C64—P4122.4 (5)
O4—C21—C22116.7 (5)C64—C65—C66120.7 (6)
O3—C21—C22113.6 (5)C64—C65—H65119.7
F3—C22—F4106.3 (5)C66—C65—H65119.7
F4'—C22—F3'106.6 (7)C67—C66—C65120.4 (6)
F3—C22—C21113.8 (5)C67—C66—H66119.8
F4'—C22—C21112.7 (6)C65—C66—H66119.8
F4—C22—C21110.9 (5)C66—C67—C68119.0 (6)
F3'—C22—C21112.7 (5)C66—C67—H67120.5
F4'—C22—Cl3'109.7 (6)C68—C67—H67120.5
F3'—C22—Cl3'106.3 (6)C67—C68—C69121.4 (6)
C21—C22—Cl3'108.5 (4)C67—C68—H68119.3
F3—C22—Cl3108.7 (4)C69—C68—H68119.3
F4—C22—Cl3107.1 (4)C64—C69—C68119.2 (6)
C21—C22—Cl3109.7 (4)C64—C69—H69120.4
C24—C23—C29118.9 (5)C68—C69—H69120.4
C24—C23—P1121.2 (4)C75—C70—C71119.1 (5)
C29—C23—P1119.8 (4)C75—C70—P4122.3 (4)
C25—C24—C23119.6 (6)C71—C70—P4118.5 (4)
C25—C24—H24120.2C70—C71—C72120.2 (5)
C23—C24—H24120.2C70—C71—H71119.9
C27—C25—C24120.6 (6)C72—C71—H71119.9
C27—C25—H25119.7C73—C72—C71120.3 (6)
C24—C25—H25119.7C73—C72—H72119.9
C28—C27—C25120.3 (6)C71—C72—H72119.9
C28—C27—H27119.9C72—C73—C74120.0 (5)
C25—C27—H27119.9C72—C73—H73120.0
C27—C28—C29119.9 (6)C74—C73—H73120.0
C27—C28—H28120.0C75—C74—C73119.6 (6)
C29—C28—H28120.0C75—C74—H74120.2
C28—C29—C23120.7 (6)C73—C74—H74120.2
C28—C29—H29119.6C70—C75—C74120.7 (5)
C23—C29—H29119.6C70—C75—H75119.6
C31—C30—C35119.0 (5)C74—C75—H75119.6
P2—Ag1—P1—C23123.5 (2)Ag1—P1—C23—C24103.9 (4)
P3—Ag1—P1—C23−112.8 (2)C30—P1—C23—C29147.4 (5)
P4—Ag1—P1—C232.3 (2)C36—P1—C23—C2941.6 (5)
P2—Ag1—P1—C30−104.56 (19)Ag1—P1—C23—C29−73.1 (5)
P3—Ag1—P1—C3019.1 (2)C29—C23—C24—C25−2.3 (8)
P4—Ag1—P1—C30134.22 (19)P1—C23—C24—C25−179.3 (4)
P2—Ag1—P1—C369.28 (17)C23—C24—C25—C270.8 (9)
P3—Ag1—P1—C36132.94 (17)C24—C25—C27—C280.3 (10)
P4—Ag1—P1—C36−111.93 (17)C25—C27—C28—C290.2 (10)
P3—Ag1—P2—C44−54.5 (2)C27—C28—C29—C23−1.7 (9)
P1—Ag1—P2—C4481.1 (2)C24—C23—C29—C282.7 (9)
P4—Ag1—P2—C44−154.87 (19)P1—C23—C29—C28179.7 (5)
P3—Ag1—P2—C37−167.73 (16)C23—P1—C30—C31134.0 (4)
P1—Ag1—P2—C37−32.09 (17)C36—P1—C30—C31−119.4 (4)
P4—Ag1—P2—C3791.94 (17)Ag1—P1—C30—C31−4.6 (5)
P3—Ag1—P2—C3877.2 (2)C23—P1—C30—C35−48.7 (5)
P1—Ag1—P2—C38−147.1 (2)C36—P1—C30—C3557.8 (5)
P4—Ag1—P2—C38−23.1 (2)Ag1—P1—C30—C35172.6 (3)
P2—Ag1—P3—C56112.5 (2)C35—C30—C31—C321.5 (7)
P1—Ag1—P3—C563.5 (2)P1—C30—C31—C32178.8 (4)
P4—Ag1—P3—C56−126.6 (2)C30—C31—C32—C33−1.0 (8)
P2—Ag1—P3—C50−17.01 (19)C31—C32—C33—C340.2 (9)
P1—Ag1—P3—C50−125.98 (18)C32—C33—C34—C350.1 (9)
P4—Ag1—P3—C50103.92 (18)C31—C30—C35—C34−1.3 (8)
P2—Ag1—P3—C62−128.67 (18)P1—C30—C35—C34−178.5 (4)
P1—Ag1—P3—C62122.37 (18)C33—C34—C35—C300.5 (8)
P4—Ag1—P3—C62−7.73 (18)C23—P1—C36—C37−104.1 (4)
P2—Ag1—P4—C70−146.3 (2)C30—P1—C36—C37149.3 (4)
P3—Ag1—P4—C7093.6 (2)Ag1—P1—C36—C3721.9 (4)
P1—Ag1—P4—C70−44.5 (2)P1—C36—C37—P2−53.8 (4)
P2—Ag1—P4—C64−17.2 (2)C44—P2—C37—C36−65.0 (4)
P3—Ag1—P4—C64−137.3 (2)C38—P2—C37—C36−172.2 (3)
P1—Ag1—P4—C6484.6 (2)Ag1—P2—C37—C3655.9 (3)
P2—Ag1—P4—C63102.96 (18)C44—P2—C38—C43−37.0 (5)
P3—Ag1—P4—C63−17.22 (18)C37—P2—C38—C4372.5 (5)
P1—Ag1—P4—C63−155.30 (17)Ag1—P2—C38—C43−173.6 (4)
C1—Sn1—O1—C19−177.6 (4)C44—P2—C38—C39141.4 (4)
C7—Sn1—O1—C1955.0 (4)C37—P2—C38—C39−109.1 (5)
C13—Sn1—O1—C19−65.3 (4)Ag1—P2—C38—C394.8 (5)
C1—Sn1—O3—C21−70.4 (4)C43—C38—C39—C400.1 (8)
C7—Sn1—O3—C2157.1 (4)P2—C38—C39—C40−178.4 (4)
C13—Sn1—O3—C21177.2 (4)C38—C39—C40—C41−0.5 (9)
C7—Sn1—C1—C6−128.5 (4)C39—C40—C41—C420.4 (9)
C13—Sn1—C1—C649.7 (5)C40—C41—C42—C430.1 (9)
O3—Sn1—C1—C6−37.8 (4)C41—C42—C43—C38−0.5 (9)
O1—Sn1—C1—C6142.7 (4)C39—C38—C43—C420.4 (8)
C7—Sn1—C1—C259.6 (5)P2—C38—C43—C42178.9 (4)
C13—Sn1—C1—C2−122.3 (4)C37—P2—C44—C49153.7 (4)
O3—Sn1—C1—C2150.3 (4)C38—P2—C44—C49−98.8 (4)
O1—Sn1—C1—C2−29.3 (4)Ag1—P2—C44—C4943.5 (4)
C6—C1—C2—C3−0.1 (8)C37—P2—C44—C45−32.1 (5)
Sn1—C1—C2—C3171.8 (4)C38—P2—C44—C4575.4 (5)
C1—C2—C3—C4−1.6 (9)Ag1—P2—C44—C45−142.3 (4)
C2—C3—C4—C52.9 (9)C49—C44—C45—C463.1 (7)
C2—C3—C4—Cl1−176.8 (4)P2—C44—C45—C46−171.1 (4)
C3—C4—C5—C6−2.5 (10)C44—C45—C46—C47−0.3 (8)
Cl1—C4—C5—C6177.3 (5)C45—C46—C47—C48−2.5 (8)
C4—C5—C6—C10.7 (10)C46—C47—C48—C492.5 (8)
C2—C1—C6—C50.6 (9)C45—C44—C49—C48−3.0 (7)
Sn1—C1—C6—C5−171.9 (5)P2—C44—C49—C48171.5 (4)
C1—Sn1—C7—C8−52.3 (5)C47—C48—C49—C440.2 (8)
C13—Sn1—C7—C8129.6 (5)C56—P3—C50—C5520.3 (5)
O3—Sn1—C7—C8−143.7 (5)C62—P3—C50—C55−88.0 (5)
O1—Sn1—C7—C833.4 (5)Ag1—P3—C50—C55159.8 (4)
C1—Sn1—C7—C12132.2 (4)C56—P3—C50—C51−157.0 (4)
C13—Sn1—C7—C12−45.8 (5)C62—P3—C50—C5194.7 (4)
O3—Sn1—C7—C1240.9 (4)Ag1—P3—C50—C51−17.5 (5)
O1—Sn1—C7—C12−142.0 (4)C55—C50—C51—C52−2.8 (8)
C12—C7—C8—C9−0.9 (8)P3—C50—C51—C52174.6 (4)
Sn1—C7—C8—C9−176.4 (4)C50—C51—C52—C531.3 (9)
C7—C8—C9—C102.4 (9)C51—C52—C53—C540.2 (9)
C8—C9—C10—C11−3.1 (9)C52—C53—C54—C55−0.1 (10)
C8—C9—C10—Cl1'179.7 (10)C51—C50—C55—C542.8 (8)
C9—C10—C11—C122.3 (9)P3—C50—C55—C54−174.5 (4)
Cl1'—C10—C11—C12179.5 (11)C53—C54—C55—C50−1.3 (9)
C10—C11—C12—C7−0.8 (9)C50—P3—C56—C57−106.0 (5)
C8—C7—C12—C110.1 (8)C62—P3—C56—C571.8 (5)
Sn1—C7—C12—C11175.7 (4)Ag1—P3—C56—C57120.8 (4)
C1—Sn1—C13—C14−104.0 (5)C50—P3—C56—C6178.2 (4)
C7—Sn1—C13—C1474.3 (5)C62—P3—C56—C61−174.0 (4)
O3—Sn1—C13—C14−14.0 (5)Ag1—P3—C56—C61−55.0 (4)
O1—Sn1—C13—C14168.9 (5)C61—C56—C57—C581.0 (8)
C1—Sn1—C13—C1874.4 (5)P3—C56—C57—C58−174.7 (4)
C7—Sn1—C13—C18−107.3 (4)C56—C57—C58—C591.1 (8)
O3—Sn1—C13—C18164.4 (4)C57—C58—C59—C60−3.0 (8)
O1—Sn1—C13—C18−12.6 (4)C58—C59—C60—C612.7 (8)
C18—C13—C14—C150.6 (9)C59—C60—C61—C56−0.6 (8)
Sn1—C13—C14—C15179.1 (5)C57—C56—C61—C60−1.3 (7)
C13—C14—C15—C160.5 (10)P3—C56—C61—C60174.7 (4)
C14—C15—C16—C17−1.2 (9)C56—P3—C62—C63171.6 (4)
C15—C16—C17—C180.7 (9)C50—P3—C62—C63−80.0 (4)
C16—C17—C18—C130.5 (9)Ag1—P3—C62—C6339.0 (4)
C14—C13—C18—C17−1.1 (8)P3—C62—C63—P4−59.8 (4)
Sn1—C13—C18—C17−179.6 (4)C70—P4—C63—C62−71.2 (4)
Sn1—O1—C19—O2−1.4 (8)C64—P4—C63—C62−176.2 (4)
Sn1—O1—C19—C20173.5 (3)Ag1—P4—C63—C6247.1 (4)
O2—C19—C20—F2−151.0 (5)C70—P4—C64—C6583.6 (5)
O1—C19—C20—F233.5 (6)C63—P4—C64—C65−169.3 (4)
O2—C19—C20—F1'−4.8 (9)Ag1—P4—C64—C65−50.1 (5)
O1—C19—C20—F1'179.6 (8)C70—P4—C64—C69−92.7 (5)
O2—C19—C20—F1−28.5 (7)C63—P4—C64—C6914.4 (5)
O1—C19—C20—F1155.9 (5)Ag1—P4—C64—C69133.6 (4)
O2—C19—C20—F2'124.1 (9)C69—C64—C65—C663.7 (9)
O1—C19—C20—F2'−51.5 (9)P4—C64—C65—C66−172.7 (4)
O2—C19—C20—Cl2'−122.3 (6)C64—C65—C66—C67−1.7 (9)
O1—C19—C20—Cl2'62.1 (6)C65—C66—C67—C68−1.2 (9)
O2—C19—C20—Cl289.9 (5)C66—C67—C68—C692.1 (10)
O1—C19—C20—Cl2−85.7 (5)C65—C64—C69—C68−2.8 (9)
Sn1—O3—C21—O44.4 (9)P4—C64—C69—C68173.5 (5)
Sn1—O3—C21—C22−174.8 (3)C67—C68—C69—C64−0.1 (10)
O4—C21—C22—F3−163.4 (5)C64—P4—C70—C7557.7 (6)
O3—C21—C22—F315.8 (7)C63—P4—C70—C75−49.9 (5)
O4—C21—C22—F4'19.4 (9)Ag1—P4—C70—C75−159.8 (5)
O3—C21—C22—F4'−161.3 (8)C64—P4—C70—C71−118.8 (5)
O4—C21—C22—F4−43.6 (8)C63—P4—C70—C71133.6 (5)
O3—C21—C22—F4135.6 (6)Ag1—P4—C70—C7123.8 (5)
O4—C21—C22—F3'140.2 (8)C75—C70—C71—C720.1 (9)
O3—C21—C22—F3'−40.6 (9)P4—C70—C71—C72176.7 (5)
O4—C21—C22—Cl3'−102.3 (6)C70—C71—C72—C73−0.1 (10)
O3—C21—C22—Cl3'76.9 (6)C71—C72—C73—C740.6 (11)
O4—C21—C22—Cl374.5 (6)C72—C73—C74—C75−1.1 (11)
O3—C21—C22—Cl3−106.2 (5)C71—C70—C75—C74−0.5 (9)
C30—P1—C23—C24−35.7 (5)P4—C70—C75—C74−177.0 (5)
C36—P1—C23—C24−141.4 (4)C73—C74—C75—C701.1 (10)
Table 1
Selected geometric parameters (°) top
C1—Sn1—C7127.5 (2)C7—Sn1—O389.9 (2)
C1—Sn1—C13112.4 (2)O1—Sn1—O3176.6 (1)
C1—Sn1—O185.5 (2)P1—Ag1—P3132.80 (5)
C7—Sn1—O191.8 (2)P2—Ag1—P4119.90 (4)
C7—Sn1—C13120.1 (2)P3—Ag1—P483.87 (5)
Acknowledgements top

We thank the University of Malaya for funding this study (SF022155/2007 A) and also for the purchase of the diffractometer.

references
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