Acta Cryst. (2008). E64, m763  [ doi:10.1107/S1600536808007861 ]

Bis(N,N'-diphenylthiourea)iodidocopper(I) monohydrate

L. Jia, L. Kong and D. Li

Abstract: In the title compound, [CuI(C₁₃H₁₂N₂S)₂]·H₂O, each Cu(I) ion is coordinated by two S atoms [Cu-S 2.2282 (16), 2.2377 (15) Å] from two N,N'-diphenylthiourea ligands and one iodide ion [Cu-I 2.5170 (11) Å] in a trigonal planar geometry. The uncoordinated water molecules are involved in N-HO hydrogen-bonding [NO 2.947 (5), 3.055 (5) Å], which link the molecules into chains extended in the [101] direction. These chains are further paired by weak intermolecular O-HS hydrogen bonds [OS 3.490 (4) Å].

Online 3 May 2008

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