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Acta Cryst. (2008). E64, m759  [ doi:10.1107/S1600536808010313 ]

catena-Poly[[bromidocopper(I)]-[mu]-[eta]2,[sigma]1-3-(2-allyl-2H-tetrazol-5-yl)pyridine]

W. Wang

Abstract: The title compound, [CuBr(C9H9N5)]n, has been prepared by the solvothermal treatment of CuBr with 3-(2-allyl-2H-tetrazol-5-yl)pyridine. It is a new homometallic CuI olefin coordination polymer in which the CuI atoms are linked by the 3-(2-allyl-2H-tetrazol-5-yl)pyridine ligands and bonded to one terminal Br atom each. The organic ligand acts as a bidentate ligand connecting two neighboring Cu centers through the N atom of the pyridine ring and the double bond of the allyl group. A three-dimensional structure is formed through weak Cu-Br [3.1579 (8) Å], C-H...Br and C-H...N interactions.

Online 3 May 2008


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