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Acta Cryst. (2008). E64, m765  [ doi:10.1107/S1600536808012282 ]

catena-Poly[[diaquamanganese(II)]-di-[mu]-pyridine-3-sulfonato-[kappa]2N:O;[kappa]2O:N]

Z.-H. Qiu, F.-P. Liang, Q.-F. Ruan and S.-R. Zhao

Abstract: In the title polymeric complex, [Mn(C5H4NO3S)2(H2O)2]n, the Mn atom is located on a centre of inversion and is coordinated by two O atoms and two N atoms derived from four different pyridine-3-sulfonate (pySO3) ligands, and two O atoms derived from two water molecules in a distorted trans-N2O4 octahedral geometry. The metal atoms are bridged by the pySO3 ligands to form a one-dimensional chain. The chains are further connected into a three-dimensional architecture via hydrogen bonds.

Online 3 May 2008


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