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Acta Cryst. (2008). E64, m788  [ doi:10.1107/S1600536808012889 ]

Dioxidobis(pentane-2,4-dionato-[kappa]2O,O')(pyridine-4-carbaldehyde oxime-[kappa]N1)uranium(VI)

T. Kawasaki and T. Kitazawa

Abstract: The title compound, [U(C5H7O2)2O2(C6H6N2O)], exhibits a pentagonal-bipyramidal coordination geometry around the UVI atom, involving two bidentate acetylacetonate ions and the pyridine ring of the pyridine-4-carbaldehyde oxime ligand. Hydrogen bonds exist between the OH group of the pyridine-4-carbaldehyde oxime ligand and the two O atoms of the acetylacetonate ions.

Online 10 May 2008


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