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Acta Cryst. (2008). E64, m828  [ doi:10.1107/S1600536808014748 ]

Chlorido(pyridine-2-carbaldehyde oximato-[kappa]2N,N')(pyridine-2-carbaldehyde oxime-[kappa]2N,N')copper(II)

G. Wu and D. Wu

Abstract: In the title compound, [Cu(C6H5N2O)Cl(C6H6N2O)], the Cu atom is coordinated by one neutral and one deprotonated pyridine-2-carboxaldehyde oxime (pco) ligand, resulting in the formation of two five-membered CuN2C2 rings. Together with the additional coordinating chloride anion, the coordination polyhedron of copper is best described as a distorted square-pyramid, the distortion parameter being 0.288. The two organic ligands are linked by an intramolecular O-H...O hydrogen bond.

Online 21 May 2008


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