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Acta Cryst. (2008). E64, o1000  [ doi:10.1107/S1600536808009598 ]

2,3-Diaminophenazine tetrahydrate

X.-F. Li, Y. An and Y.-S. Yin

Abstract: The title compound, C12H10N4·4H2O, was obtained from a room-temperature solution of o-phenylenediamine and copper acetate. In the crystal structure, there are significant [pi]-[pi] stacking interactions, with a centroid-centroid separation of 3.575 (2) Å. In addition, intermolecular O-H...O, N-H...O, N-H...N and O-H...N hydrogen bonds link 2,3-diaminophenazine molecules and water molecules, forming a three-dimensional framework.

Online 7 May 2008


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