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Acta Cryst. (2008). E64, m785  [ doi:10.1107/S1600536808012853 ]

Poly[[{[mu]4-1,2-bis[(3-cyanobenzylidene)hydrazono]-1,2-diphenylethane}bis(trifluoromethanesulfonato)disilver(I)] benzene solvate]

H. L. Li

Abstract: In the title complex, {[Ag2(CF3O3S)2(C30H20N6)]·C6H6}n, the two independent AgI ions are each coordinated by two N atoms and one O atom in a `T-shaped' geometry. In the crystal structure, 1,2-bis[(3-cyanobenzylidene)hydrazono]-1,2-diphenylethane ligands act as bridging ligands and each coordinates to four AgI ions, resulting in a one-dimensional chain structure. The crystal structure is stabilized by weak intermolecular C-H...O hydrogen bonds.

Online 7 May 2008


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