Acta Cryst. (2008). E64, m827  [ doi:10.1107/S1600536808014499 ]

Tetrakis(1,1,1-trifluoroacetylacetonato-²O,O')zirconium(IV) toluene solvate

M. Steyn, A. Roodt and G. Steyl

Abstract: In the title compound, [Zr(C₅H₄F₃O₂)₄]·C₇H₈, the Zr atom is in a square-antiprismatic coordination geometry that comprises four O,O'-bidentate trifluoroacetylacetonate ligands. The O-Zr-O bite angles of the acetonate ligands range from 75.27 (5) to 75.41 (5)°. The Zr atom is located on a twofold rotation axis.

Online 21 May 2008

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