Acta Cryst. (2008). E64, m832  [ doi:10.1107/S1600536808014888 ]

Tetra-n-butylammonium iodido(pyrrolidine-1-carbodithioato-²S,S')(tris-tert-butoxysilanethiolato-S)cadmate(II)

A. Kropidlowska, J. Chojnacki and B. Becker

Abstract: In the anion of the title compound, (C₁₆H₃₆N)[Cd(C₅H₈NS₂)(C₁₂H₂₇O₃SSi)I], the Cd atom is four-coordinated by S,S'-chelating dithiocarbamate, S-donating silanethiolate and iodide ligands in a distorted tetrahedral environment . Intermolecular C-H S and C-HI interactions between cations and anions are present. Two C atoms of a tert-butyl group are disordered over two positions; the site occupancies are ca 0.65 and 0.35.

Online 21 May 2008

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