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Acta Cryst. (2008). E64, o988-o989  [ doi:10.1107/S1600536808012671 ]

(E)-4-(Benzyloxy)benzaldehyde thiosemicarbazone

M. T. H. Tarafder, M. A. A. A. A. Islam, K. A. Crouse, S. Chantrapromma and H.-K. Fun

Abstract: In the title compound, C15H15N3OS, the thiosemicarbazone group adopts an E configuration with respect to the C=N bond. The benzaldehyde thiosemicarbazone fragment is almost planar [maximum deviation = 0.012 (1) Å], while the dihedral angle between the benzyloxy and phenyl rings is 72.48 (5)°. In the crystal structure, molecules are interconnected by N-H...N and N-H...S hydrogen bonds, forming a two-dimensional network parallel to the bc plane and are further stacked along the a axis by [pi]-[pi] interactions [centroid-centroid separation 3.9043 (7) Å]. The crystal structure is also stabilized by C-H...[pi] interactions.

Online 3 May 2008


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