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Volume 64 
Part 7 
Page m857  
July 2008  

Received 18 May 2008
Accepted 26 May 2008
Online 7 June 2008

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Key indicators
Single-crystal X-ray study
T = 292 K
Mean [sigma](C-C) = 0.005 Å
R = 0.030
wR = 0.066
Data-to-parameter ratio = 15.3
Details
Open access

[2-(1,3-Dithiolan-2-ylidene)-5-(4-methylphenyl)-3-oxopent-4-enoato-[kappa]O]triphenyltin(IV)

Ze-Min Meia* and Wei Fanga

aDepartment of Chemistry, BaiCheng Normal College, BaiCheng 137000, People's Republic of China
Correspondence e-mail: fangwei1026@yahoo.com.cn

In the title compound, [Sn(C6H5)3(C17H17O3S2)], the SnIV atom adopts a distorted tetrahedral SnC3O geometry. A short intramolecular Sn...O contact of 2.793 (2) Å also occurs.

Related literature

For related literature, see: James et al. (1992[James, B. D., Gioskos, S., Chandra, S., Magee, R. J. & Cashion, J. D. (1992). J. Organomet. Chem. 436, 155-167.]).

[Scheme 1]

Experimental

Crystal data

  • [Sn(C6H5)3(C17H17O3S2)]

  • Mr = 683.42

  • Monoclinic, P 21 /c

  • a = 12.736 (3) Å

  • b = 14.945 (3) Å

  • c = 17.733 (4) Å

  • [beta] = 106.85 (3)°

  • V = 3230.4 (11) Å3

  • Z = 4

  • Mo K[alpha] radiation

  • [mu] = 0.95 mm-1

  • T = 292 (2) K

  • 0.43 × 0.21 × 0.08 mm
Data collection

  • Bruker APEX diffractometer

  • Absorption correction: multi-scan (SADABS; Bruker, 2002[Bruker (2002). SMART, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]) Tmin = 0.793, Tmax = 0.943

  • 7230 measured reflections

  • 5654 independent reflections

  • 4186 reflections with I > 2[sigma](I)

  • Rint = 0.017
Refinement

  • R[F2 > 2[sigma](F2)] = 0.029

  • wR(F2) = 0.066

  • S = 0.91

  • 5654 reflections

  • 370 parameters

  • H-atom parameters constrained

  • [Delta][rho]max = 0.32 e Å-3

  • [Delta][rho]min = -0.25 e Å-3

Table 1
Selected bond lengths (Å)

Sn-O1 2.0716 (19)
Sn-C13 2.121 (3)
Sn-C1 2.128 (3)
Sn-C7 2.135 (3)

Data collection: SMART (Bruker, 2002[Bruker (2002). SMART, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]); cell refinement: SAINT (Bruker, 2002[Bruker (2002). SMART, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: SHELXTL (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); software used to prepare material for publication: SHELXTL.

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: HB2734 ).

Acknowledgements

The authors thank BaiCheng Normal College for supporting this work.

References

Bruker (2002). SMART, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.
James, B. D., Gioskos, S., Chandra, S., Magee, R. J. & Cashion, J. D. (1992). J. Organomet. Chem. 436, 155-167.  [CrossRef] [ChemPort]
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.  [CrossRef] [details]

Acta Cryst (2008). E64, m857  [ doi:10.1107/S1600536808015754 ]

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