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Volume 64 
Part 8 
Page m1035  
August 2008  

Received 28 June 2008
Accepted 14 July 2008
Online 16 July 2008

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Key indicators
Single-crystal X-ray study
T = 295 K
Mean [sigma](C-C) = 0.011 Å
R = 0.054
wR = 0.142
Data-to-parameter ratio = 19.2
Details
Open access

Tricyclohexyl(piperidine-1-dithiocarboxylato-[kappa]S)tin(IV)

Lujiang Hao,a* Chunhua Mub and Binbin Konga

aCollege of Food and Biological Engineering, Shandong Institute of Light Industry, Jinan 250353, People's Republic of China, and bMaize Research Insitute, Shandong Academy of Agricultural Science, Jinan 250100, People's Republic of China
Correspondence e-mail: lujianghao001@yahoo.com.cn

In the title compound, [Sn(C6H11)3(C6H10NS2)], the SnIV atom is tetracoordinated by three C atoms from cyclohexyl groups and one S atom from a piperidinedithiocarboxylate anion. The coordination geometry is distorted tetrahedral, with Sn-C bond lengths in the range 2.133 (6)-2.188 (6) Å and with an Sn-S bond length of 2.4516 (19) Å. The nonbonded S atom of the piperidinedithiocarboxylate anion makes an Sn...S contact of 3.174 (3) Å.

Related literature

For related literature, see: Church & Halvorson (1959[Church, B. S. & Halvorson, H. (1959). Nature (London), 183, 124-125.]); Chung et al. (1971[Chung, L., Rajan, K. S., Merdinger, E. & Crecz, N. (1971). Biophys. J. 11, 469-475.]); Okabe & Oya (2000[Okabe, N. & Oya, N. (2000). Acta Cryst. C56, 1416-1417.]); Serre et al. (2005[Serre, C., Marrot, J. & Ferey, G. (2005). Inorg. Chem. 44, 654-658.]); Pocker & Fong (1980[Pocker, Y. & Fong, C. T. O. (1980). Biochemistry, 19, 2045-2049.]); Scapin et al. (1997[Scapin, G., Reddy, S. G., Zheng, R. & Blanchard, J. S. (1997). Biochemistry, 36, 15081-15088.]).

[Scheme 1]

Experimental

Crystal data

  • [Sn(C6H11)3(C6H10NS2)]

  • Mr = 528.40

  • Monoclinic, P 21 /c

  • a = 17.227 (8) Å

  • b = 7.676 (4) Å

  • c = 20.827 (10) Å

  • [beta] = 109.598 (8)°

  • V = 2594 (2) Å3

  • Z = 4

  • Mo K[alpha] radiation

  • [mu] = 1.16 mm-1

  • T = 295 (2) K

  • 0.26 × 0.20 × 0.12 mm
Data collection

  • Bruker APEXII CCD diffractometer

  • Absorption correction: multi-scan (SADABS; Bruker, 2001[Bruker (2001). SAINT-Plus and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]) Tmin = 0.753, Tmax = 0.874

  • 22395 measured reflections

  • 4846 independent reflections

  • 3085 reflections with I > 2[sigma](I)

  • Rint = 0.081
Refinement

  • R[F2 > 2[sigma](F2)] = 0.053

  • wR(F2) = 0.141

  • S = 1.04

  • 4846 reflections

  • 253 parameters

  • 36 restraints

  • H-atom parameters constrained

  • [Delta][rho]max = 0.76 e Å-3

  • [Delta][rho]min = -0.66 e Å-3

Data collection: APEX2 (Bruker, 2004[Bruker (2004). APEX2. Bruker AXS Inc., Madison, Wisconsin, USA.]); cell refinement: SAINT-Plus (Bruker, 2001[Bruker (2001). SAINT-Plus and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]); data reduction: SAINT-Plus; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: SHELXTL (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); software used to prepare material for publication: SHELXTL.

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: BI2291 ).

Acknowledgements

This work is supported by the Natural Science Foundation of Shandong Province (grant No. Y2007D39).

References

Bruker (2001). SAINT-Plus and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.
Bruker (2004). APEX2. Bruker AXS Inc., Madison, Wisconsin, USA.
Chung, L., Rajan, K. S., Merdinger, E. & Crecz, N. (1971). Biophys. J. 11, 469-475.  [CrossRef] [ChemPort] [ISI] [PubMed]
Church, B. S. & Halvorson, H. (1959). Nature (London), 183, 124-125.  [CrossRef] [PubMed] [ChemPort] [ISI]
Okabe, N. & Oya, N. (2000). Acta Cryst. C56, 1416-1417.  [CSD] [CrossRef] [ChemPort] [details]
Pocker, Y. & Fong, C. T. O. (1980). Biochemistry, 19, 2045-2049.  [CrossRef] [ChemPort] [PubMed] [ISI]
Scapin, G., Reddy, S. G., Zheng, R. & Blanchard, J. S. (1997). Biochemistry, 36, 15081-15088.  [CrossRef] [ChemPort] [PubMed] [ISI]
Serre, C., Marrot, J. & Ferey, G. (2005). Inorg. Chem. 44, 654-658.  [ISI] [CSD] [CrossRef] [PubMed] [ChemPort]
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.  [CrossRef] [details]

Acta Cryst (2008). E64, m1035  [ doi:10.1107/S1600536808021909 ]

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