Acta Cryst. (2008). E64, m1080  [ doi:10.1107/S1600536808023349 ]

Diazidobis{2-[3-(dimethylamino)propyliminomethyl]phenol}manganese(III) perchlorate

G.-B. Yang and Z.-H. Sun

Abstract: The title compound, [Mn(N₃)₂(C₁₂H₁₈N₂O)₂]ClO₄, was synthesized from manganese(III) acetate, sodium azide and 2-[3-(dimethylamino)propyliminomethyl]phenol by a hydrothermal reaction. The Mn^III ion is hexacoordinated by two N and two O atoms from two phenolate ligands and two N atoms from two azide ligands. The Mn^III cation lies on an inversion centre and, as a result, the asymmetric unit comprises one half-molecule.

Online 31 July 2008

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