Acta Cryst. (2008). E64, m1080 [ doi:10.1107/S1600536808023349 ]
Abstract: The title compound, [Mn(N3)2(C12H18N2O)2]ClO4, was synthesized from manganese(III) acetate, sodium azide and 2-[3-(dimethylamino)propyliminomethyl]phenol by a hydrothermal reaction. The MnIII ion is hexacoordinated by two N and two O atoms from two phenolate ligands and two N atoms from two azide ligands. The MnIII cation lies on an inversion centre and, as a result, the asymmetric unit comprises one half-molecule.
Online 31 July 2008
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