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Acta Cryst. (2008). E64, m986  [ doi:10.1107/S1600536808019843 ]

Triaqua(3-carboxy-5-sulfonatobenzoato-[kappa]O1)(1,10-phenanthroline-[kappa]2N,N')cobalt(II) monohydrate

B.-Y. Zhang, J.-J. Nie and D.-J. Xu

Abstract: In the title compound, [Co(C8H4O7S)(C12H8N2)(H2O)3]·H2O, the CoII cation is coordinated by one sulfoisophthalate dianion, one bidentate phenathroline (phen) molecule and three water molecules in a distorted cis-CoN2O4 octahedral geometry. In the crystal structure, aromatic [pi]-[pi] stacking occurs [centroid-centroid distances 3.7630 (14) and 3.7269 (15) Å], as well as an extensive O-H...O and C-H...O hydrogen-bonding network

Online 5 July 2008


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