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Acta Cryst. (2008). E64, o1453-o1454  [ doi:10.1107/S1600536808020734 ]

1-Methyl-2-[(E)-2-(2-thienyl)ethenyl]quinolinium iodide

P. Ruanwas, T. Kobkeatthawin, S. Chantrapromma, H.-K. Fun and C. Karalai

Abstract: In the title compound, C16H14NS+·I-, the cation has an E configuration about the C=C double bond of the ethylene unit. The dihedral angle between the thiophene ring and the quinolinium ring system is 11.67 (11)°. A weak C-H...S intramolecular interaction involving the thiophene ring generates an S(5) ring motif. In the crystal structure, the iodide ion, located between the cations arranged in an antiparallel manner, forms weak C-H...I interactions. The crystal structure is further stabilized by a [pi]-[pi] interaction between the thiophene and pyridine rings; the centroid-centroid distance is 3.6818 (13) Å.

Online 9 July 2008


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