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Volume 64 
Part 9 
Page m1137  
September 2008  

Received 11 July 2008
Accepted 1 August 2008
Online 6 August 2008

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Key indicators
Single-crystal X-ray study
T = 296 K
Mean [sigma](C-C) = 0.005 Å
R = 0.032
wR = 0.113
Data-to-parameter ratio = 17.1
Details
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catena-Poly[[diaqua[(4-tolylsulfanyl)acetato-[kappa]O]cadmium(II)]-[mu]-4,4'-bipyridine-[kappa]2N:N']

Wen-Xuan Cai,a+ Xiao-Yong Zheng,a++ Xiao-Hong Genga and Yun-Long Fenga*

aZhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004, People's Republic of China
Correspondence e-mail: sky37@zjnu.cn

The title complex, [Cd(C9H9O2S)2(C10H8N2)(H2O)2]n, has a linear chain structure. The central CdII ion is in a slightly disorted octahedral environment, coordinated by two aqua ligands, two (4-tolylsulfanyl)acetate ligands and two bridging 4,4'-bipyridine ligands. The CdII ion lies on a twofold rotation axis. Intermolecular O-H...O hydrogen bonds connect adjacent chains, forming a layer structure. An intramolecular O-H...O hydrogen bond is also present.

Related literature

For related literature, see: Lin et al. (2006[Lin, H., Su, H. & Feng, Y. (2006). Acta Cryst. E62, m747-m749.]); Zheng et al. (2006[Zheng, X.-Y., Su, H. & Feng, Y.-L. (2006). Acta Cryst. E62, m1393-m1394.]).

[Scheme 1]

Experimental

Crystal data

  • [Cd(C9H9O2S)2(C10H8N2)(H2O)2]

  • Mr = 667.09

  • Monoclinic, C 2/c

  • a = 21.659 (4) Å

  • b = 11.590 (2) Å

  • c = 11.137 (2) Å

  • [beta] = 93.88 (3)°

  • V = 2789.3 (9) Å3

  • Z = 4

  • Mo K[alpha] radiation

  • [mu] = 0.98 mm-1

  • T = 296 (2) K

  • 0.40 × 0.35 × 0.17 mm
Data collection

  • Bruker APEXII area-detector diffractometer

  • Absorption correction: multi-scan (SADABS; Sheldrick, 1996[Sheldrick, G. M. (1996). SADABS. University of Göttingen, Germany.]) Tmin = 0.68, Tmax = 0.85

  • 12185 measured reflections

  • 3154 independent reflections

  • 2937 reflections with I > 2[sigma](I)

  • Rint = 0.017
Refinement

  • R[F2 > 2[sigma](F2)] = 0.032

  • wR(F2) = 0.112

  • S = 1.12

  • 3154 reflections

  • 184 parameters

  • 3 restraints

  • H atoms treated by a mixture of independent and constrained refinement

  • [Delta][rho]max = 0.60 e Å-3

  • [Delta][rho]min = -0.37 e Å-3

Table 1
Hydrogen-bond geometry (Å, °)

D-H...A D-H H...A D...A D-H...A
O1W-H1WA...O2 0.82 1.94 2.667 (4) 148
O1W-H1WB...O1i 0.805 (17) 2.04 (2) 2.782 (3) 154 (4)
Symmetry code: (i) [x, -y, z+{\script{1\over 2}}].

Data collection: APEX2 (Bruker, 2006[Bruker (2006). SMART and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.]); cell refinement: SAINT (Bruker, 2006[Bruker (2006). SMART and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.]); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: SHELXTL (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); software used to prepare material for publication: SHELXTL.

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: AT2595 ).

References

Bruker (2006). SMART and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.
Lin, H., Su, H. & Feng, Y. (2006). Acta Cryst. E62, m747-m749.  [CSD] [CrossRef] [details]
Sheldrick, G. M. (1996). SADABS. University of Göttingen, Germany.
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.  [CrossRef] [details]
Zheng, X.-Y., Su, H. & Feng, Y.-L. (2006). Acta Cryst. E62, m1393-m1394.  [CSD] [CrossRef] [details]

Acta Cryst (2008). E64, m1137  [ doi:10.1107/S1600536808024720 ]

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