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Acta Cryst. (2008). E64, m1186  [ doi:10.1107/S1600536808026081 ]

trans-Aqua(4,7-diazadecane-1,10-diamine-[kappa]4N)fluoridochromium(III) bis(perchlorate) monohydrate

J.-H. Choi and U. Lee

Abstract: In the title compound, [CrF(C8H20N4)(H2O)](ClO4)2·H2O, the Cr atom is in a slightly distorted octahedral environment, coordinated by four N atoms of the 4,7-diazadecane-1,10-diamine ligand, one water molecule and an F atom trans to water. The five-membered chelate ring is in a gauche form, while the two six-membered chelate rings are in chair conformations. The crystal structure is stabilized by several hydrogen bonds.

Online 20 August 2008


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