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Acta Cryst. (2008). E64, m1162-m1163 [ doi:10.1107/S1600536808025579 ]
![[mu]](/logos/entities/mu_rmgif.gif)
2-4-aminobenzenesulfonato-![[kappa]](/logos/entities/kappa_rmgif.gif)
2N:O)diaquamanganese(II)] dihydrate]Abstract: The title compound, {[Mn(NH2C6H4SO3)2(H2O)2]·2H2O}n, was prepared under mild hydrothermal conditions. The unique MnII ion is located on a crystallographic inversion center and is coordinated by two -NH2 and two -SO3 groups from four 4-aminobenzenesulfonate ligands and by two water molecules in the axial positions, forming a slightly distorted octahedral coordination environment. The 4-aminobenzenesulfonate anions behave as 2-bridging ligands to produce a two-dimensional structure. In the crystal structure, intermolecular N-H
O, O-HO and C-HO hydrogen bonds link the layers into a three-dimensional network.
Online 13 August 2008
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