Acta Cryst. (2008). E64, m1154-m1155  [ doi:10.1107/S1600536808024951 ]

Tris[tris(ethane-1,2-diamine)cobalt(II)] bis[octacyanidomolybdate(V)] dihydrate

C.-X. Chu, H. Zhou, L. Liu and A.-H. Yuan

Abstract: In the title compound, [Co^II(C₂H₈N₂)₃]₃[Mo^V(CN)₈]₂·2H₂O, N-HN and N-HO hydrogen-bonding interactions give rise to a three-dimensional network. In the crystal structure, each Mo polyhedron has a square-antiprismatic shape, while the Co complexes show distorted octahedral geometry with an occupancy of 50%. One of the Co atoms resides on a crystallographic inversion centre.

Online 13 August 2008

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