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Acta Cryst. (2008). E64, o1858-o1859 [ doi:10.1107/S160053680802727X ]
Abstract: In the title compound, C8H11N2S+·C12H10NO3S-, the NH group of the S-benzylthiuronium is protonated and the interplanar angle between the phenyl ring and the CH2-S=C(NH2)2 unit is 47.44 (10)°. In the 4-anilinobenzenesulfonate anion, the interplanar angle between the two rings is 44.07 (8)°. In the crystal structure, anions are linked into chains along the c-axis direction by N-H
O hydrogen bonds, while additional N-H
O interactions link the cations to the anions in chains along the b-axis direction. These chains are further interconnected into a two-dimensional network parallel to the bc plane by C-H
O interactions. C-H
contacts are also observed.
Online 30 August 2008
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