Received 5 August 2008
The asymmetric unit of the title compound, [Mn(ClO4)(C30H34N6)]ClO4, consists of a cationic [Mn(ClO4)(C30H34N6)]+ complex and a perchlorate anion. In the complex, the Mn2+ ion is seven-coordinated in an approximately pentagonal-bipyramidal environment by six N atoms from the hexadentate N,N,N',N'-tetrakis(2-pyridylmethyl)cyclohexane-1,2-diamine (tpdach) ligand and one O atom from a perchlorate anion. The complex displays intermolecular - interactions between adjacent pyridine rings (centroid-to-centroid distance 4.133 Å). Moreover, there are weak intra- and intermolecular C-HO hydrogen bonds. The Cl atom and two O atoms of the perchlorate are disordered, with a site-occupancy factor of 0.59 (2) for the major component.
Data collection: SMART (Bruker, 2000); cell refinement: SAINT (Bruker, 2000); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: ORTEP-3 (Farrugia, 1997) and PLATON (Spek, 2003); software used to prepare material for publication: SHELXL97.
Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: ZL2134 ).
This work was supported by a Korea Research Foundation Grant funded by the Korean Government (MOEHRD) (KRF-2007-412-J02001).
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