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Volume 64 
Part 10 
Page m1325  
October 2008  

Received 16 September 2008
Accepted 18 September 2008
Online 27 September 2008

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Key indicators
Single-crystal X-ray study
T = 100 K
Mean [sigma](C-C) = 0.007 Å
R = 0.024
wR = 0.064
Data-to-parameter ratio = 17.3
Details
Open access

Chlorido(dimethyl sulfoxide-[kappa]S)[2-(2-pyridyl)phenyl-[kappa]2N,C1]platinum(II)

Masayuki Kobayashi,a Shigeyuki Masaokaa and Ken Sakaia*

aDepartment of Chemistry, Faculty of Science, Kyushu University, Hakozaki 6-10-1, Higashi-ku, Fukuoka 812-8581, Japan
Correspondence e-mail: ksakai@chem.kyushu-univ.jp

In the title compound, [Pt(C11H8N)Cl(C2H6OS)], the S atom of dimethyl sulfoxide is trans to the pyridyl N atom [Pt-S = 2.2181 (11) Å] and the chlorido ligand is trans to the carbon donor of 2-(2-pyridyl)phenyl [Pt-Cl = 2.4202 (10) Å]. The [2-(2-pyridyl)phenyl]platinum(II) unit forms a one-dimensional stack along the c axis with two independent interplanar separations of 3.44 (9) and 3.50 (2) Å.

Related literature

For background information, see: Herber et al. (1994[Herber, R. H., Croft, M., Coyer, M. J., Bilash, B. & Sahiner, A. (1994). Inorg. Chem. 33, 2422-2426.]); Mdleleni et al. (1995[Mdleleni, M. M., Bridgewater, J. S., Watts, R. J. & Ford, P. C. (1995). Inorg. Chem. 34, 2334-2342.]); Newman et al. (2007[Newman, C. P., Casey-Green, K., Clarkson, G. J., Cave, G. W. V., Errington, W. & Rourke, J. P. (2007). Dalton Trans. pp. 3170-3182.]); Ozawa et al. (2006[Ozawa, H., Haga, M. & Sakai, K. (2006). J. Am. Chem. Soc. 128, 4926-4927.], 2007[Ozawa, H., Yokoyama, Y., Haga, M. & Sakai, K. (2007). Dalton Trans. pp. 1197-1206.]); Sakai & Ozawa (2007[Sakai, K. & Ozawa, H. (2007). Coord. Chem. Rev. 251, 2753-2766.]); Sakai et al. (1993[Sakai, K., Kizaki, Y., Tsubomura, T. & Matumoto, K. (1993). J. Mol. Catal. 79, 141-152.]); Ozawa & Sakai (2007[Ozawa, H. & Sakai, K. (2007). Chem. Lett. 36, 920-921.]); Kobayashi et al. (2008[Kobayashi, M., Masaoka, M. & Sakai, K. (2008). Photochem. Photobiol. Sci. Submitted.]).

[Scheme 1]

Experimental

Crystal data

  • [Pt(C11H8N)Cl(C2H6OS)]

  • Mr = 462.85

  • Monoclinic, C 2/c

  • a = 22.414 (3) Å

  • b = 10.0205 (16) Å

  • c = 14.057 (2) Å

  • [beta] = 124.512 (2)°

  • V = 2601.6 (7) Å3

  • Z = 8

  • Mo K[alpha] radiation

  • [mu] = 11.14 mm-1

  • T = 100 (2) K

  • 0.09 × 0.08 × 0.04 mm
Data collection

  • Bruker SMART APEXII CCD-detector diffractometer

  • Absorption correction: multi-scan (SADABS; Sheldrick, 1996[Sheldrick, G. M. (1996). SADABS. University of Göttingen, Germany.]) Tmin = 0.486, Tmax = 0.640

  • 7004 measured reflections

  • 2850 independent reflections

  • 2448 reflections with I > 2[sigma](I)

  • Rint = 0.018
Refinement

  • R[F2 > 2[sigma](F2)] = 0.023

  • wR(F2) = 0.064

  • S = 1.11

  • 2850 reflections

  • 165 parameters

  • H-atom parameters constrained

  • [Delta][rho]max = 2.05 e Å-3

  • [Delta][rho]min = -1.43 e Å-3

Data collection: APEX2 (Bruker, 2006[Bruker (2006). APEX2. Bruker AXS Inc., Madison, Wisconsin, USA.]); cell refinement: APEX2; data reduction: SAINT (Bruker, 2004[Bruker (2004). SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.]); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: KENX (Sakai, 2004[Sakai, K. (2004). KENX. Kyushu University, Japan.]); software used to prepare material for publication: SHELXL97, TEXSAN (Molecular Structure Corporation, 2001[Molecular Structure Corporation (2001). TEXSAN. MSC, The Woodlands, Texas, USA.]), KENX and ORTEPII (Johnson, 1976[Johnson, C. K. (1976). ORTEPII. Report ORNL-5138. Oak Ridge National Laboratory, Tennessee, USA.]).

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: AT2633 ).

Acknowledgements

This work was in part supported by a Grant-in-Aid for Scientific Research (A) (No. 17205008), a Grant-in-Aid for Specially Promoted Research (No. 18002016), and a Grant-in-Aid for the Global COE Program (`Science for Future Molecular Systems') from the Ministry of Education, Culture, Sports, Science, and Technology of Japan.

References

Bruker (2004). SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.
Bruker (2006). APEX2. Bruker AXS Inc., Madison, Wisconsin, USA.
Herber, R. H., Croft, M., Coyer, M. J., Bilash, B. & Sahiner, A. (1994). Inorg. Chem. 33, 2422-2426.  [CrossRef] [ChemPort] [ISI]
Johnson, C. K. (1976). ORTEPII. Report ORNL-5138. Oak Ridge National Laboratory, Tennessee, USA.
Kobayashi, M., Masaoka, M. & Sakai, K. (2008). Photochem. Photobiol. Sci. Submitted.
Mdleleni, M. M., Bridgewater, J. S., Watts, R. J. & Ford, P. C. (1995). Inorg. Chem. 34, 2334-2342.  [CrossRef] [ChemPort] [ISI]
Molecular Structure Corporation (2001). TEXSAN. MSC, The Woodlands, Texas, USA.
Newman, C. P., Casey-Green, K., Clarkson, G. J., Cave, G. W. V., Errington, W. & Rourke, J. P. (2007). Dalton Trans. pp. 3170-3182.  [CrossRef]
Ozawa, H., Haga, M. & Sakai, K. (2006). J. Am. Chem. Soc. 128, 4926-4927.  [ISI] [CrossRef] [PubMed] [ChemPort]
Ozawa, H. & Sakai, K. (2007). Chem. Lett. 36, 920-921.  [CrossRef] [ChemPort]
Ozawa, H., Yokoyama, Y., Haga, M. & Sakai, K. (2007). Dalton Trans. pp. 1197-1206.  [CrossRef]
Sakai, K. (2004). KENX. Kyushu University, Japan.
Sakai, K., Kizaki, Y., Tsubomura, T. & Matumoto, K. (1993). J. Mol. Catal. 79, 141-152.  [ChemPort]
Sakai, K. & Ozawa, H. (2007). Coord. Chem. Rev. 251, 2753-2766.  [ISI] [CrossRef] [ChemPort]
Sheldrick, G. M. (1996). SADABS. University of Göttingen, Germany.
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.  [CrossRef] [details]

Acta Cryst (2008). E64, m1325  [ doi:10.1107/S1600536808030109 ]

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